炭纤维涂层改性对快速制备C<sub>f</sub>/SiC复合材料力学性能的影响

摘要
图/表
参考文献
相关文章 (5)

全文: PDF (1367 KB) HTML (1 KB)
输出: BibTeX | EndNote (RIS)

摘要以SiC粉末、酚醛树脂粉末及有PyC/SiC复合涂层改性和无涂层改性的两种炭纤维毡/布为原料,采用新型快速成形工艺结合反应熔体浸渗技术制备C_f/SiC复合材料,并对其表面化学气相沉积(chemical vapor deposition(CVD))/SiC涂层。通过XRD物相分析、扫描电镜及复合材料力学性能测试等手段,研究炭纤维涂层改性及表面涂层改性对C_f/SiC复合材料力学性能的影响。结果表明：涂层改性的炭纤维在反应熔渗过程中不被液Si侵蚀,从而提高材料的力学性能;表面CVD SiC涂层改性能够通过填补表面缺陷,包覆易裂部位,涂层脱粘,弥补内部缺陷等方式提高抗弯强度;采用PyC/SiC复合涂层对炭纤维改性后,复合材料抗弯强度由150.90 MPa提高到217.96 MPa,通过表面CVD SiC涂层后,复合材料抗弯强度进一步提高,达到266.94 MPa。

	服务

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	孙晔华
	李国栋
	叶国柱
	史琦
	张洋
	何岸青

关键词 ： C_f/SiC复合材料, 化学气相沉积, 界面改性, 表面改性, 抗弯强度

Abstract：C_f/SiC composites were fabricated by new rapid forming process and reactive melt infiltration, using SiC powder, phenolic resin powder and coated as well as uncoated carbon fiber felt/cloth as raw materials. Then the surface of C_f/SiC composites were coated by chemical vapor deposition (CVD) SiC coating. The effects of coating modification of the carbon fiber and surface coating on the mechanical properties of C_f/SiC composite were studied by XRD phase analysis, scanning electron microscopy (SEM) and mechanical properties test of composite. The results show that CVD PyC/SiC composite interface coating can improve the mechanical properties of the composite materials by protecting carbon fibers from liquid Si corrosion during reactive melt infiltration. CVD SiC surface coating can improve the bending strength of C_f/SiC composite by filling surface defects, cladding fragile parts, coating debonding and remedying internal defects. The bending strength of carbon fiber with PyC/SiC composites coating increases from 150.90 MPa to 217.96 MPa. By means of CVD SiC surface coating, the bending strength is further improved to 266.94 MPa.

Key words： C_f/SiC composite CVD (chemical vapor deposition) interface coating surface coating bending strength

收稿日期: 2018-11-23 出版日期: 2019-07-11

ZTFLH:

TB332

通讯作者: 李国栋,教授,博士。电话：13087317973;E-mail: lgd63@163.com

引用本文:

孙晔华, 李国栋, 叶国柱, 史琦, 张洋, 何岸青. 炭纤维涂层改性对快速制备C_f/SiC复合材料力学性能的影响[J]. 粉末冶金材料科学与工程, 2019, 24(3): 248-254.
SUN Yehua, LI Guodong, YE Guozhu, SHI Qi, ZHANG Yang, HE Anqing. Effect of carbon fiber coating modification on mechanical properties of rapidly prepared C_f/SiC composite. Materials Science and Engineering of Powder Metallurgy, 2019, 24(3): 248-254.

链接本文:

http://pmbjb.csu.edu.cn/CN/ 或 http://pmbjb.csu.edu.cn/CN/Y2019/V24/I3/248

[1] 邹世钦, 张长瑞, 周新贵, 等. 连续纤维增强陶瓷基复合材料在航空发动机上的应用[J]. 航空发动机, 2005, 31(3): 55-58.
ZOU Shiqin, ZHANG Changrui, ZHOU Xingui, et al.Application of continuous fiber reinforced ceramic matrix composites in aeroengine[J]. Aeroengine, 2005, 31(3): 55-58.
[2] FAN S, ZHANG L, CHENG L, et al.Microstructure and frictional properties of C/SiC brake materials with sandwich structure[J]. Ceramics International, 2011, 37(7): 2829-2835.
[3] PADTURE N P.Advanced structural ceramics in aerospace propulsion[J]. Nature Materials, 2016, 15(8): 804.
[4] 张玉娣, 周新贵, 张长瑞. C_f/SiC陶瓷基复合材料的发展与应用现状[J]. 材料工程, 2005(4): 60-63.
ZHANG Yudi, ZHOU Xingui, ZHANG Changrui.Development and application of C_f/SiC ceramic matrix composites[J]. Journal of Materials Engineering, 2005(4): 60-63.
[5] XUAN Z, ZHU D, QIAO X, et al.Friction and wear properties of C/C-SiC braking composites[J]. Tribology, 2012, 38(3): 2467-2473.
[6] 张勇, 冯涤, 陈希春. 连续纤维增强SiC 复合材料制备工艺与性能研究进展[J]. 材料导报, 2005, 19(3): 63-66.
ZHANG Yong, FENG Di, CHEN Xichun.Development of properties and process on continuous fiber reinforced SiC composite[J]. Materials Review, 2005, 19(3): 63-66.
[7] XIANG Y, LI W, WANG S, et al.Ablation behavior and mechanism of SiC/Zr-Si-C multilayer coating for PIP-C/SiC composites under oxyacetylene torch flame[J]. Composites Part B, 2015, 69: 127-132.
[8] UHLMANN F, WILHELMI C, SCHMIDT-WIMMER S, et al.Preparation and characterization of ZrB₂ and TaC containing C f /SiC composites via Polymer-Infiltration-Pyrolysis process[J]. Journal of the European Ceramic Society, 2017, 37(5): 1955-1960.
[9] KUMAR S, BABLU M, RANJAN A, et al.Fabrication of 2D C/C-SiC composites using PIP based hybrid process and investigation of mechanical properties degradation under cyclic heating[J]. Ceramics International, 2017, 43(3): 3414-3423.
[10] 焦健, 刘善华. 化学气相渗透工艺(CVI)制备陶瓷基复合材料的进展研究[J]. 航空制造技术, 2015, 483(14): 101-104.
JIAO Jian, LIU Shanhua.Progress in ceramic matrix composites fabricated by chemical vapor infiltration (CVI) process[J]. Aeronautical Manufacturing Technology, 2015, 483(14): 101-104.
[11] 张波, 李瑞珍, 解惠贞. 熔融渗硅法制备C/C-SiC复合材料工艺参数研究[J]. 材料导报, 2015(S1): 389-392.
ZHANG Bo, LI Ruizhen, XIE Huizhen.Research of the parameter of liquid silicon in filtration process for C/C-SiC composites[J]. Materials Review, 2015(S1): 389-392.
[12] 刘跃, 付前刚, 李贺军, 等. 反应熔体渗透法制备C/C-SiC复合材料的微观结构及抗氧化性能[J]. 中国材料进展, 2016, 35(2): 128-135.
LIU Yue, FU Qianqiang, LI Hejun, et al.Microstructure and oxidation resistance of C/C-SiC composites prepared by reactive melt infiltration[J]. Materials China, 2016, 35(2): 128-135.
[13] ZHONG W, WANG S, LI J, et al.Design of carbon fiber reinforced boron nitride matrix composites by vacuum-assisted polyborazylene transfer molding and pyrolysis[J]. Journal of the European Ceramic Society, 2013, 33(15/16): 2979-2992.
[14] KRENKEL W,BERNDT F.C/C-Si C composites for space applications and advanced friction systems[J]. Mater Sci Eng, A, 2005, 412(1/2): 177-181.
[15] PATEL M, SAURABH K, PRASAD B V V, et al. High temperature C/C-Si C composite by liquid silicon infiltration: a literature review[J]. Bull Mater Sci, 2012, 35(1): 67-77.
[16] KRENKEL W.Ceramic Matrix Composites: Fiber Reinforced Ceramics and Their Applications[M]. WILEY-VCH Verlag Gm-b H & Co KGa A, 2008: 73-80.
[17] SHEN A Q, GLEASON B, MCKINLEY G H, et al.Fiber coating with surfactant solutions[J]. Physics of Fluids, 2002, 14(11): 4055-4068.
[18] 代吉祥, 沙建军, 王首豪, 等. 纤维表面状态对C/C-SiC复合材料微观组织和相成分的影响[J]. 航空学报, 2015, 36(5): 1704-1712.
DAI Jixiang, SHA Jianjun, WANG Shouhao, et al.Influence of fiber surface state on microstructure and phase composition of C/C-SiC composites[J]. Acta Aeronautica ET Astronautica Sinica, 2015, 36(5): 1704-1712.
[19] 刘荣军, 曹英斌, 龙宪海, 等. 先驱体浸渍-裂解SiC界面改性涂层对气相渗硅3D-C_f/SiC复合材料力学性能的影响[J]. 复合材料学报, 2016, 33(6): 1266-1273.
LIU Rongjun, CAO Yingbin, LONG Xianhai, et al.Effects of precursor infiltration pyrolysis SiC interphase modified coating on mechanical properties of 3D-C_f/SiC composites prepared by gaseous silicon infiltration process[J]. Acta Materiae Compositae Sinica 2016, 33(6): 1266-1273.
[20] 刘荣军, 曹英斌, 杨会永, 等. CVD-SiC界面改性涂层对气相渗硅制备C_f/SiC复合材料力学性能的影响[J]. 材料工程, 2018, 46(1): 37-43.
LIU Rongjun, CAO Yingbin, YANG Huiyong, et al.Effect of CVD-SiC interface modification coating on the mechanical properties of C_f/SiC composite prepared by gaseous silicon infiltration process[J]. Journal of Materials Engineering, 2018, 46(1): 37-43.
[21] 湖南兴晟新材料科技有限公司. 炭纤维增强碳化硅陶瓷基复合材料及其制备方法[P].CN. A, 201910091540.8, 2019.
Hunan Xingsheng New Matterials Technology Co., Ltd.Carbon fiber reinforced silicon carbide ceramic matrix composites and their preparation methods[P]. CN. A, 201910091540.8, 2019.