水热法制备酚醛树脂球模板尺寸对ZnFe<sub>2</sub>O<sub>4</sub>空心球磁性能的影响

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摘要以间苯二酚和甲醛为反应剂,氨水为催化剂,无水乙醇为分散剂,采用水热法制备酚醛树脂球,然后以酚醛树脂球为模板,以硝酸铁和硝酸锌为原料,制备ZnFe₂O₄铁氧体空心球。对酚醛树脂球的结构、形貌和粒度以及ZnFe₂O₄球的晶体结构、化学组成、微观形貌与磁性能进行表征,研究模板球尺寸对锌铁氧体磁性能的影响。结果表明：随搅拌速度增加或甲醛用量减少,酚醛树脂球的尺寸减小。通过控制反应体系中原料的比例和用量,可得到不同尺寸、表面光滑、球形度高、尺寸均一、单分散性好,表面含有大量羟基官能团的酚醛树脂球。ZnFe₂O₄为结晶良好的立方尖晶石型结构,为规则的空心球,分散性好、尺寸均一。随模板尺寸减小,ZnFe₂O₄球的尺寸逐渐减小,呈现出铁磁性向顺磁性的转变,饱和磁化强度(Ms)增加。当模板尺寸为271.8 nm时,ZnFe₂O₄纳米空心球的饱和磁化强度为5.4 (A·m²)/kg。

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	王志龙
	葛毅成
	冉丽萍
	易茂中

关键词 ：模板法, 酚醛树脂球, 锌铁氧体, 粒度, 磁性能

Abstract：The phenolic resin microspheres using resorcinol and formaldehyde as reactants, ammonia as catalyst and anhydrous ethanol as dispersant were prepared by hydrothermal method. The hollow ferrite was prepared templated by phenolic resin microspheres, using ferric nitrate and zinc nitrate, ferric chloride and zinc chloride as precursors, respectively. The structure, morphology and particle size of phenolic resin spheres, as well as the crystal structure, chemical composition, micromorphology and magnetic properties of ZnFe₂O₄ spheres were characterized. The effect of template sphere size on the magnetic properties of zinc ferrite was investigated. The results show that the size of the phenolic resin sphere decreases with the stirring speed increasing or the amount of formaldehyde decreasing. The phenolic resin balls of different sizes can be obtained by controlling the proportion and amount of raw materials in the reaction system, the spherical surface is smooth, the sphericity is high, the size is uniform, and the monodispersity is good, and the surface contains a large amount of hydroxyl functional groups. ZnFe₂O₄ is a well-crystallized cubic spinel structure, which is a regular hollow sphere with good dispersibility and uniform size. As the size of the template decreases, the size of the ZnFe₂O₄ sphere gradually decreases, and it turn out the ferromagnetism transit to paramagnetic, and the saturation magnetization (Ms) gradually increases. When the template size is 271.8 nm, the saturation magnetization of the ZnFe₂O₄ sphere is 5.4 (A∙m²)/kg.

Key words： template method phenolic resin ball zinc ferrite particle size magnetic properties

收稿日期: 2018-10-22 出版日期: 2019-07-12

ZTFLH:

TB303

基金资助:国家自然科学基金资助项目(51574293); 粉末冶金国家重点实验室自主研究课题(2017)

作者简介: 葛毅成,副教授,博士。电话：13507105471;E-mail: hncsgyc@csu.edu.cn

引用本文:

王志龙, 葛毅成, 冉丽萍, 易茂中. 水热法制备酚醛树脂球模板尺寸对ZnFe₂O₄空心球磁性能的影响[J]. 粉末冶金材料科学与工程, 2019, 24(2): 137-146.
WANG Zhilong, GE Yicheng, RAN Liping, YI Maozhong. Effect of template size of phenolic resin spheres prepared by hydrothermal method on the magnetic properties of ZnFe₂O₄ hollow spheres. Materials Science and Engineering of Powder Metallurgy, 2019, 24(2): 137-146.

链接本文:

http://pmbjb.csu.edu.cn/CN/ 或 http://pmbjb.csu.edu.cn/CN/Y2019/V24/I2/137

[1] RAHIMI R, KERDARI H, RABBANI M, et al.Synthesis, characterization and adsorbing properties of hollow Zn-Fe₂O₄ nanospheres on removal of congo red from aqueous solution[J]. Desalination, 2011, 280(1/3): 412-418.
[2] IBRAHIM I, ALI I O, SALAMA T M, et al.Synthesis of magnetically recyclable spinel ferrite (MFe₂O₄, M=Zn, Co, Mn) nanocrystals engineered by sol gel-hydrothermal technology: High catalytic performances for nitroarenes reduction[J]. Applied Catalysis B: Environmental, 2016, 181(14): 389-402.
[3] HWANG H, SHIN H, LEE W J.Effects of calcination temperature for rate capability of triple-shelled ZnFe₂O₄ hollow microspheres for lithium ion battery anodes[J]. Sci Rep, 2017, 7: 46378.
[4] YAO Lingmin, HOU Xianhua, HU Shejun, et al.A facile bubble-assisted synthesis of porous Zn ferrite hollow microsphere and their excellent performance as an anode in lithium ion battery[J]. Journal of Solid State Electrochemistry, 2013, 17(7): 2055-2060.
[5] ZHU Jian, XU Zhi, LU Bingan.Ultrafine Au nanoparticles decorated NiCo₂O₄ nanotubes as anode material for high- performance supercapacitor and lithium-ion battery applications[J]. Nano Energy, 2014, 7(1): 114-123.
[6] WANG Mingyue, HUANG Ying, CHEN Xuefang, et al.Synthesis of nitrogen and sulfur co-doped graphene supported hollow ZnFe₂O₄ nanosphere composites for application in lithium-ion batteries[J]. Journal of Alloys & Compounds, 2017, 691: 407-415.
[7] SONG Xuezhi, QIAO Liang, SUN Kaiming, et al.Triple-shelled ZnO/ZnFe₂O₄ heterojunctional hollow microspheres derived from prussian blue analogue as high-performance acetone sensors[J]. Sensors and Actuators B: Chemical, 2018, 256: 374-382.
[8] ZHOU X, WANG B, SUN H, et al.Template-free synthesis of hierarchical ZnFe₂O₄ yolk-shell microspheres for high-sensitivity acetone sensors[J]. Nanoscale, 2016, 8(10): 5446-5453.
[9] ZHU Y, LEI J, TIAN Y.Uniform iron oxide hollow spheres for high-performance delivery of insoluble anticancer drugs[J]. Dalton Trans, 2014, 43(19): 7275-7281.
[10] REMYA N S, SYAMA S, SABAREESWARAN A, et al.Toxicity, toxicokinetics and biodistribution of dextran stabilized iron oxide nanoparticles for biomedical applications[J]. Int J Pharm, 2016, 511(1): 586-596.
[11] WU J, DENG A, JIANG W, et al.Synthesis and in vitro evaluation of pH-sensitive magnetic nanocomposites as methotrexate delivery system for targeted cancer therapy[J]. Mater Sci Eng C Mater Biol Appl, 2017, 71: 132-140.
[12] HOQUE S M, HOSSAIN M S, CHOUDHURY S, et al.Synthesis and characterization of ZnFe₂O₄ nanoparticles and its biomedical applications[J]. Mater Lett, 2016, 162: 60-63.
[13] HAYASHI K, SATO Y, SAKAMOTO W, et al.Theranostic nanoparticles for MRI-guided thermo chemotherapy: “Tight” clustering of magnetic nanoparticles boosts relaxivity and heat- generation power[J]. Acs Biomater Sci Eng, 2017, 3(1): 95-105.
[14] 段红珍, 陈国红, 周芳灵, 等. 纳米镍钴铁氧体空心球的制备与性能[J]. 无机化学学报, 2015, 31(11): 2181-2187.
DUAN Hongzhen, CHEN Guohong, ZHOU Fangling, et al.Preparation and properties of nanocrystalline nickel-cobalt ferrite hollow microspheres[J]. Journal of Inorganic Chemistry, 2015, 31(11): 2181-2187
[15] LI Lindong, LIU Sida, LU Longfei.Synthesis and significantly enhanced microwave absorption properties of cobalt ferrite hollow microspheres with protrusions/polythiophene composites[J]. Journal of Alloys and Compounds, 2017, 722: 158-165.
[16] LI Zhibin, DENG Yida, SHEN Bin, et al.Preparation and microwave absorption properties of Ni-Fe₃O₄ hollow spheres[J]. Materials Science and Engineering: B, 2009, 164(2): 112-115.
[17] GUO X, LU X, FANG X, et al.Lithium storage in hollow spherical ZnFe₂O₄ as anode materials for lithium ion batteries[J]. Electrochemistry Communications, 2010, 12(6): 847-50.
[18] LI J, LIU Z, ZHU Z.Magnetically separable ZnFe₂O₄, Fe₂O₃/ ZnFe₂O₄ and ZnO/ZnFe₂O₄ hollow nanospheres with enhanced visible photocatalytic properties[J]. RSC Adv, 2014, 4(93): 51302-51308.
[19] AIGUO, YAN X L, RAN YI, et al. Selective synthesis and properties of monodisperse Zn ferrite hollow nanospheres and nanosheets[J]. J Phys Chem C, 2008, 112: 8558-8563.
[20] GENG H, ZHAO Y, LIU J, et al.Hollow mesoporous silica as a high drug loading carrier for regulation insoluble drug release[J]. Int J Pharm, 2016, 510(1): 184-194.
[21] FENG Jiantao, WANG Yechen, HOU Yanhui, et al.Tunable design of yolk-shell ZnFe₂O₄@RGO@TiO₂ microspheres for enhanced high-frequency microwave absorption[J]. Inorg Chem Front, 2017, 4(6): 935-945.
[22] WU Niandu, LIU Xianguo, ZHAO Chengyun, et al.Effects of particle size on the magnetic and microwave absorption properties of carbon-coated nickel nanocapsules[J]. Journal of Alloys and Compounds, 2016, 656: 628-634.
[23] YAN Juntao, GAO Shenyuan, WANG Chunlei, et al.A facile electrospinning and direct annealing method for the fabrication of multi-porous ZnFe₂O₄ nanotubes with enhanced photocatalytic activity[J]. Mater Lett, 2016, 184: 43-46.
[24] YAN Qingbin, LI Shijia, PANG Ernan, et al.Fabrication of hollow spheres FeCo alloy through a hydrothermal reduction method[J]. Mater Lett, 2014, 120: 185-188.
[25] KURIAN J, MATHEW M J.Structural, optical and magnetic studies of CuFe₂O₄, MgFe₂O₄ and ZnFe₂O₄ nanoparticles prepared by hydrothermal/solvothermal method[J]. Journal of Magnetism and Magnetic Materials, 2018, 451: 121-130.