Anti-oxidation property of 88WC-12Co coating prepared by high velocity oxy-fuel spraying
LIU Baogang, MA Qilin, LIU Chao, PENG Xinke, ZHU Xiaoyun, JI Qing
School of Energy and Electromechanical Engineering, Hunan University of Humanities, Science and Technology,Hunan Provincial Key Laboratory of Fine Ceramics and Powder Materials, Loudi 417000, China
Abstract:A high density 88WC-12Co coating was prepared on the surface of 45# steel by high velocity oxy-fuel (HVOF). The microstructures, phases, and micro-hardness of the coatings after spraying and oxidation were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and micro-hardness tester respectively. The oxidation mechanism of the coating material was also discussed. The results show that 88WC-12Co coating has excellent oxidation resistance under 500 ℃, and the micro-hardness of the coating changes little after oxidation. However, the WO3 and CoWO4 phases significantly increased above 500 ℃, and the oxidation resistance and micro-hardness of the coating decreased obviously. The oxidation mechanism of the coating materials is that WC, W2C and Co in the coating react with O2 in the air to form WO3 and CoWO4 under high temperature.
刘宝刚, 马启林, 刘超, 彭馨可, 朱肖运, 季晴. 超音速火焰喷涂88WC-12Co涂层的抗氧化性能[J]. 粉末冶金材料科学与工程, 2018, 23(4): 422-426.
LIU Baogang, MA Qilin, LIU Chao, PENG Xinke, ZHU Xiaoyun, JI Qing. Anti-oxidation property of 88WC-12Co coating prepared by high velocity oxy-fuel spraying. Materials Science and Engineering of Powder Metallurgy, 2018, 23(4): 422-426.
[1] CHIVAVIBUL P, WATANABE M, KURODA S, et al.Effects of carbide size and Co content on the microstructure and mechanical properties of HVOF-sprayed WC-Co coatings[J]. Surface and Coatings Technology, 2007, 202(3): 509-521. [2] FAN Z S, WANG S S, ZHANG Z D.Microstructures and properties of nano-structural WC-12Co coatings deposited by AC-HVAF[J]. Rare Metal Materials and Engineering, 2017, 46(4): 0923-0927. [3] VALENTINELLI L, VALENTE T, CASADEI F, et a1. Mechanical and tribocorrosion properties of HVOF sprayed WC-Co coatings[J]. Corrosion Engineering Science and Technology, 2015, 39(4): 301-307. [4] MAGNANI M, SUEGAMA P H, ESPALLARGAS N, et al.Influence of HVOF parameters on the corrosion and wear resistance of WC-Co coatings sprayed on AA7050 T7[J]. Surface and Coatings Technology, 2008, 202(19): 4746-4757. [5] JAFARI M,ENAYATI M H, SALEHI M, et al.Influence of nickel-coated nanostructured WC-Co powders on microstructural and tribological properties of HVOF coatings[J]. Journal of Thermal Spray Technology, 2014, 23(8): 1456-1469. [6] 鲍君峰, 崔颖, 侯玉柏, 等. 超音速热喷涂技术的发展与现状[J]. 热喷涂技术, 2011, 3(4): 18-21. BAO Junfeng, CUI Ying, HOU Yubai, et al.Perspective and application of nanophase WC-Co powder[J]. Thermal Spray Technology, 2011, 3(4): 18-21. [7] LI M, SHI D, CHRISTOFIDES P D.Modeling and control of HVOF thermal spray processing of WC-Co coatings[J]. Powder Technology, 2005, 156(2/3): 177-194. [8] MA N, CHENG Z X, WU H T, et al. HVOF spraying process optimization for the deposition of submicron structuralWC-12Co coatings[J]. Advanced Materials Research, 2013, 785-786: 839-843. [9] 王海滨, 宋晓艳, 高杨, 等. 超音速火焰喷涂法制备超细结构WC-Co涂层及其结构与性能表征[J]. 粉末冶金材料科学与工程, 2011, 16(4): 492-497. WANG Haibin, SONG Xiaoyan, GAO Yang, et al.Fabrication of ultrafine-structured WC-Co coating by high velocity oxy-fuel spraying method and characterizations on microstructure and performance[J]. Materials Science and Engineering of Powder Metallurgy, 2011, 16(4): 492-497. [10] 孙策, 陆冠雄, 郭磊, 等. HVOF喷涂WC-12Co粒子在不同基体上的沉积行为[J]. 稀有金属材料与工程, 2016, 45(3): 749-754. SUN Ce, LU Guanxiong, GUO Lei, et al.Deposition behavior of WC-12Co particles on different substrates sprayed by HVOF[J]. Rare Metal Materials and Engineering, 2016, 45(3): 749-754. [11] 王进春, 孔德军. 超音速火焰喷涂WC-12Co涂层高温摩擦-磨损性能[J]. 中南大学学报(自然科学版), 2017, 48(3): 608-616. WANG Jinchun, KONG Dejun.Friction-wear properties of HVOF sprayed WC-12Co coatings at high temperatures[J]. Journal of Central South University (Science and Technology), 2017, 48(3): 608-616. [12] SELVADURAI U, HOLLINGSWORTH P, BAUMANN I, et al.Influence of the handling parameters on residual stresses of HVOF-sprayed WC-12Co coatings[J]. Surface and Coatings Technology, 2015, 268(8): 30-35. [13] COUTO M, DOSTA S, GUILEMANY J M.Comparison of the mechanical and electrochemical properties of WC-17and 12Co coatings ontoAl7075-T6 obtained by high velocity oxy-fuel and cold gas spraying[J]. Surface and Coatings Technology, 2015, 268(8): 180-189. [14] BOLELLI G, BORNER T, MILANTI A, et al.Tribological behavior of HVOF- and HVAF-sprayed composite coatings based on Fe-alloy+WC-12%Co[J]. Surface and Coatings Technology, 2014, 248(13): 104-112. [15] ZHANG W C, LIU L B, ZHANG M T, et al.Comparison between WC-10Co-4Cr and Cr3C2-25Ni Cr coatings sprayed on H13 steel by HVOF[J]. Trans. Nonferrous Met Soc China, 2015, 25: 3700-3707. [16] HONG S, WU Y P, GAO W W, et al.Microstructural characterisation and microhardness distribution of HVOF sprayed WC-10Co-4Cr coating[J]. Surface Engineering, 2014, 30(1): 53-58. [17] CHEN L Y, YI D Q, WANG B, et al.The selective oxidation behaviour of WC-Co cemented carbides during the early oxidation stage[J]. Corrosion Science, 2015, 94: 1-5. [18] CHEN L Y, YI D Q, WANG B, et al.Mechanism of the early stages of oxidation of WC-Co cemented carbides[J]. Corrosion Science, 2016, 103: 75-87. [19] GU W H, JEONG Y S, KIM K, et al.Thermal oxidation behavior of WC-Co hard metal machining tool tip scraps[J]. Journal of Materials Processing Technology, 2012, 212: 1250-1256. [20] 郑亚军. Ti(Cr,Al)SiC(O)N涂层及其表面改性硬质合金刀具性能研究[D]. 成都: 西南交通大学, 2013: 1-73. ZHENG Yajun.The properties of Ti(Cr,Al)SiC(O)N coatings and the coated cemented carbide tools[D]. Chengdu: Southwest Jiaotong University, 2013: 1-73.