氩气雾化Sc、Y微合金化René104镍基高温合金粉末的组织与性能

doi:10.19976/j.cnki.43-1448/TF.2022054

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摘要采用氩气雾化法制备Sc、Y微合金化René104镍基高温合金粉末,分析粉末的粒径分布、形貌、显微组织与性能。结果表明：氩气雾化粉末球形度高,卫星粉和异形粉少,粒径小于53 μm的粉末收得率(质量分数)高达52.52%。粉末内部结构致密,显微组织为等轴晶+树枝晶,晶界处出现Ti、Nb、Ta、Mo元素的偏析。经过Sc、Y微合金化的René104镍基高温合金雾化粉末性能得到改善,流动性好,松装密度高,显微硬度、纳米硬度(HV)和弹性模量分别达到360±6、(6.5±0.4) GPa和(102.1±10.6) GPa。

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	曹镔
	刘祖铭
	王建川
	魏冰
	周欢
	张亚洲

关键词 ：氩气雾化, 镍基高温合金, 微合金化, 显微组织, 粉末性能

Abstract：Sc, Y microalloyed René104 nickel-based superalloy powders were prepared by argon atomization. The particle size distribution, morphology, microstructure and properties of the powders were analyzed. The results show that the argon atomized powders have high sphericity with less satellite powders and irregular powders, and the yield (mass fraction) of the powders with particle size less than 53 μm is as high as 52.52%. The interior microstructure of the powder is dense, showing both equiaxial grain and dendrite morphology. Ti, Nb, Ta and Mo segregate at the grain boundary. By Sc, Y microalloying, the properties of René104 nickel-based superalloy powders have been improved, with good flow ability and high apparent density. Microhardness, nanohardness (HV) and elastic modulus of the powders are 360±6, (6.5±0.4) GPa and (102.1±10.6 ) GPa, respectively.

Key words： argon atomization nickel-based superalloy microalloying microstructure powder property

收稿日期: 2022-04-28 出版日期: 2023-05-04

ZTFLH:

TG146

基金资助:金属材料磨损控制与成型技术国家地方联合工程研究中心开放基金资助项目(HKDNM201907); 粉末冶金国家重点实验室自主课题

通讯作者: 刘祖铭,教授,博士。电话：0731-88836355;E-mail: lzm@csu.edu.cn

引用本文:

曹镔, 刘祖铭, 王建川, 魏冰, 周欢, 张亚洲. 氩气雾化Sc、Y微合金化René104镍基高温合金粉末的组织与性能[J]. 粉末冶金材料科学与工程, 2023, 28(2): 192-202.
CAO Bin, LIU Zuming, WANG Jianchuan, WEI Bing, ZHOU Huan, ZHANG Yazhou. Microstructure and properties of Sc, Y microalloyed René104 nickel-based superalloy powders prepared by argon atomization. Materials Science and Engineering of Powder Metallurgy, 2023, 28(2): 192-202.

链接本文:

http://pmbjb.csu.edu.cn/CN/10.19976/j.cnki.43-1448/TF.2022054 或 http://pmbjb.csu.edu.cn/CN/Y2023/V28/I2/192

[1] ANVARI A.Failure of Nickel-based super alloy (ME3) in aerospace gas turbine engines[J]. Journal of Chemical Engineering and Materials Science, 2017, 8(6): 46-65.
[2] CARTER J L W, KUPER M W, UCHIC M D, et al. Characterization of localized deformation near grain boundaries of superalloy René-104 at elevated temperature[J]. Materials Science and Engineering A, 2014, 605: 127-136.
[3] 贾建, 陶宇, 张义文, 等. 第三代粉末冶金高温合金René104的研究进展[J]. 粉末冶金工业, 2007, 17(3): 36-43.
JIA Jian, TAO Yu, ZHANG Yiwen, et al.Rencent devlopment of third generation P/M superalloy René104[J]. Powder Metallurgy Technology, 2007, 17(3): 36-43.
[4] TOMUS D, TIAN Y, ROMETSCH P A, et al.Influence of post heat treatments on anisotropy of mechanical behaviour and microstructure of Hastelloy-X parts produced by selective laser melting[J]. Materials Science and Engineering A, 2016, 667: 42-53.
[5] WANG H, ZHANG X, WANG G B, et al.Selective laser melting of the hard-to-weld IN738LC superalloy: efforts to mitigate defects and the resultant microstructural and mechanical properties[J]. Journal of Alloys and Compounds, 2019, 807: 151662.
[6] NADAMMAL N, CABEZA S, MISHUROVA T, et al.Effect of hatch length on the development of microstructure, texture and residual stresses in selective laser melted superalloy Inconel 718[J]. Materials & Design, 2017, 134: 139-150.
[7] NGUEJIO J, SZMYTKA F, HALLAIS S, et al.Comparison of microstructure features and mechanical properties for additive manufactured and wrought nickel alloys 625[J]. Materials Science and Engineering A, 2019, 764: 138214
[8] YANG J, LI F, WANG Z, et al.Cracking behavior and control of Rene 104 superalloy produced by direct laser fabrication[J]. Journal of Materials Processing Technology, 2015, 225: 229-239.
[9] PENG K, DUAN R X, LIU Z M, et al.Cracking behavior of René 104 nickel-based superalloy prepared by selective laser melting using different scanning strategies[J]. Materials, 2020, 13(9): 2149.
[10] YING W, HAN F, WANG J.Effects of preheating and cooling on the crack defects of laser solid formed Rene 104 superalloy parts[J]. Journal of Engineering Manufacture, 2020, 234(8): 1087-1101.
[11] 段然曦, 黄伯云, 刘祖铭, 等. René104镍基高温合金选区激光熔化成形及开裂行为[J]. 中国有色金属学报, 2018. 28(8): 1568-1578.
DUAN Ranxi, HUANG Baiyun, LIU Zuming, et al.Selective laser melting fabrication and cracking behavior of René104 nickel-based superalloy[J]. Transactions of Nonferrous Metals Society of China, 2018, 28(8): 1568-1578.
[12] GERSTGRASSER M, CLOOTS M, STIRNIMANN J, et al.Focus shift analysis, to manufacture dense and crack-free SLM-processed CM247LC samples[J]. Journal of Materials Processing Technology, 2020, 289: 116948.
[13] QIU C, WANG Z, ALADAWI A S, et al.Influence of laser processing strategy and remelting on surface structure and porosity development during selective laser melting of a metallic material[J]. Metallurgical and Materials Transactions A, 2019, 50(9): 4423-4434.
[14] SENTYURINA Z A, BASKOV F A, LOGINOV P A, et al.The effect of hot isostatic pressing and heat treatment on the microstructure and properties of EP741NP nickel alloy manufactured by laser powder bed fusion[J]. Additive Manufacturing, 2020, 37: 101629.
[15] HARRISON N J, TODD I, MUMTAZ K.Reduction of micro-cracking in nickel superalloys processed by selective laser melting: a fundamental alloy design approach[J]. Acta Materialia, 2015, 94: 59-68.
[16] KONTIS P, CHAUVET E, PENG Z, et al.Atomic-scale grain boundary engineering to overcome hot-cracking in additively- manufactured superalloys[J]. Acta Materialia, 2019, 177: 209-221.
[17] 彭凯. René104镍基高温合金的选区激光熔化成形及缺陷研究[D]. 长沙: 中南大学, 2019.
PENG Kai.Selective laser melting fabrication and defect control of René104 nickel-based superalloy[D]. Changsha: Central South University, 2019.
[18] ZHOU W, ZHU G, WANG R, et al.Inhibition of cracking by grain boundary modification in a non-weldable nickel-based superalloy processed by laser powder bed fusion[J]. Materials Science and Engineering A, 2020, 791: 139745.
[19] HAN Q, GU Y, GU H, et al.Laser powder bed fusion of WC-reinforced Hastelloy-X composite: microstructure and mechanical properties[J]. Journal of Materials Science, 2021, 56(2): 1768-1782.
[20] WEI B, LIU Z, CAO B, et al.Cracking inhibition of nano-TiC reinforced René 104 superalloy fabricated by selective laser melting[J]. Journal of Alloys and Compounds, 2021, 881: 160413.
[21] GHOUSSOUB J N, KLUPŚ P, DICK-CLELAND W J B, et al. A new class of alumina-forming superalloy for 3D printing[J]. Additive Manufacturing, 2022, 52: 102608.
[22] 农必重. 选区激光熔融制备René104镍基高温合金裂纹形成机理及其控制[D]. 长沙: 中南大学, 2021.
NONG Bizhong.Crack formation mechanism and control of René104 nickel-base superalloy fabricated by selective laser melting[D]. Changsha: Central South University, 2021.
[23] BIAN W, ZHANG H, ZHANG X, et al.Comprehensive influence of Y on K417 superalloy: purification, interactions among the alloy elements and high temperature properties[J]. Materials Science and Engineering A, 2019, 755: 190-200.
[24] KANG D S, KOIZUMI Y, YAMANAKA K, et al.Significant impact of yttrium microaddition on high temperature tensile properties of Inconel 713C superalloy[J]. Materials Letters, 2018, 227: 40-43.
[25] KAKEHI K, BANOTH S, KUO Y L, et al.Effect of yttrium addition on creep properties of a Ni-base superalloy built up by selective laser melting[J]. Scripta Materialia, 2020, 183: 71-74.
[26] GUAN K, HUANG Z, CUI R, et al.Effects of yttrium on microstructure and mechanical properties of a directionally solidified single crystal superalloy[J]. Materials Science and Engineering A, 2019, 752: 86-92.
[27] PAN X L, YU H Y, TU G F, et al.Effect of rare earth metals on solidification behaviour in nickel based superalloy[J]. Materials Science and Technology, 2013, 28(5): 560-564.
[28] 金玉花, 韩萍花, 李常锋, 等. 稀土Y,Ce对K418镍基高温合金微观组织的影响[J]. 材料工程, 2016, 44(3): 46-51.
JIN Yuhua, HAN Pinghua, LI Changfeng, et al.Effect of rare earth element (Y, Ce) on microstructure of K418 Ni-base superalloy[J]. Journal of Materials Engineering, 2016, 44(3): 46-51.
[29] WEI B, LIU Z M, CAO B, et al.Selective laser melting of crack-free René 104 superalloy by Sc microalloying[J]. Journal of Alloys and Compounds, 2022, 895: 162663.
[30] BRIKA S E, LETENNEUR M, DION C A, et al.Influence of particle morphology and size distribution on the powder flow ability and laser powder bed fusion manufacturability of Ti-6Al-4V alloy[J]. Additive Manufacturing, 2020, 31: 100929.
[31] 李响, 曾克里, 何鹏江, 等. 雾化压力对选区激光熔化用Inconel 625合金粉末粒度与形貌的影响[J]. 粉末冶金材料科学与工程, 2019, 24(4): 374-378.
LI Xiang, ZENG Keli, HE Pengjiang, et al.Effect of atomization pressure on particle size and morphology of Inconel 625 alloy powder for selective laser melting[J]. Materials Science and Engineering of Powder Metallurgy, 2019, 24(4): 374-378.
[32] 段然曦. 选区激光熔化成形René104镍基高温合金的组织及力学性能研究[D]. 长沙: 中南大学, 2017.
DUAN Ranxi.The microstructure and mechanical properties of René104 nickel-based superalloy fabricated by selective laser melting[D]. Changsha: Central South University, 2017.
[33] WEI B, CAO B, LIU Z M, et al.Additive manufacturing of Sc microalloyed René 104 superalloy: powder properties and cracking elimination[J]. Advanced Powder Technology, 2022, 33(2): 103430.
[34] 苏鹏飞, 刘祖铭, 郭旸, 等. 氩气雾化René104镍基高温合金粉末的显微组织和凝固缺陷[J]. 中南大学学报(自然科学版), 2018, 49(1): 64-71.
SU Pengfei, LIU Zuming, GUO Yang, et al.Microstructure and solidification defect of René104 nickel-based superalloy powder atomized by argon gas atomization[J]. Journal of Central South University (Nature Science Edition), 2018, 49(1): 64-71.
[35] GHAYOOR M, LEE K, HE Y, et al.Selective laser melting of 304L stainless steel: role of volumetric energy density on the microstructure, texture and mechanical properties[J]. Additive Manufacturing, 2020, 32: 101011.
[36] 许阳, 张荣, 肖志瑜. Inconel 718合金粉末粒形定量表征及其SLM成形工艺优化[J]. 粉末冶金材料科学与工程, 2020, 25(6): 465-474.
XU Yang, ZHANG Rong, XIAO Zhiyu, et al.Quantitative characterization of Inconel 718 alloy powder particle shape and optimization of its SLM forming process[J]. Materials Science and Engineering of Powder Metallurgy, 2019, 24(4): 374-378.
[37] YAN F, XIONG W, FAIERSON E.Grain structure control of additively manufactured metallic materials[J]. Materials, 2017, 10(11): 1260.
[38] BERMINGHAM M J, STJOHN D H, KRYNEN J, et al.Promoting the columnar to equiaxed transition and grain refinement of titanium alloys during additive manufacturing[J]. Acta Materialia, 2019, 168: 261-274.
[39] GUIMARÃES A V, DA SILVEIRA R M S, DE ALMEIDA L H, et al. Influence of yttrium addition on the microstructural evolution and mechanical properties of superalloy 718[J]. Materials Science and Engineering A, 2020, 776: 139023.
[40] DENG R, LIU F, TAN L, et al.Effects of scandium on microstructure and mechanical properties of RR1000[J]. Journal of Alloys and Compounds, 2019, 785: 634-641.
[41] BONACHE V, RAYÓN E, SALVADOR M D, et al. Nanoindentation study of WC-12Co hardmetals obtained from nanocrystalline powders: evaluation of hardness and modulus on individual phases[J]. Materials Science and Engineering A, 2010, 527(12): 2935-2941.
[42] 中国国家标准化管理委员会. 金属材料硬度和材料参数的仪器化压入试验第1部分: 试验方法GB/T 21838.1—2019[S]. 北京: 中国标准出版社, 2019-08-30.
Standardization Administration of the People’s Republic of China. Metallic materials— instrumented indentation test for hardness and materials parameter: part 1 Test method: GB/T 21838.1—2019[S]. Beijing: Standards Press of China, 2019-08-30.