Abstract:Two-stage heat treatment/deformation processing with solution/cold-rolling and aging/cold-rolling of Cu-Cr-Zr alloy prepared by SPS was carried out, the microstructure, mechanical properties and electrical conductivity of the alloy were investigated. The results show that the SPSed Cu-Cr-Zr alloy matrix structure with uniform composition and fine grains, as well as the multi-scale of nano and sub-micron and multi-structure second phase with uniform distribution on the matrix were obtained by solution treated at 980 ℃ for 50 min, cold-rolled at 30% deformation, aged at 450 C for 2 h and cold-rolled at 70% deformation. The interactions of precipitation strengthening of the multi-scale second phase and strain hardening improved the strength and conductivity of the Cu-Cr-Zr alloy, and its tensile strength and electrical conductivity were 625 MPa and 79%IACS respectively, which were 143% and 20% higher than that of SPSed alloy.
[1] MISHNEV R, SHAKHOVA I, BELYAKOV A, et al.Deformation microstructures, strengthening mechanisms, and electrical conductivity in a Cu-Cr-Zr alloy[J]. Materials Science and Engineering A, 2015, 629: 29-40. [2] LIU Q, ZHANG X, GE Y, et al.Effect of processing and heat treatment on behavior of Cu-Cr-Zr alloys to railway contact wire[J]. Metallurgical and Materials Transactions A, 2006, 37(11): 3233-3238. [3] CHBIHI A, SAUVAGE X, BLAVETTE D.Atomic scale investigation of Cr precipitation in copper[J]. Acta Materialia, 2012, 60(11): 4575-4585. [4] WANG Z, ZHONG Y, LEI Z, et al.Microstructure and electrical conductivity of Cu-Cr-Zr alloy aged with dc electric current[J]. Journal of Alloys and Compounds, 2009, 471(1/2): 172-175. [5] WANG Z, ZHONG Y, CAO G, et al.Influence of dc electric current on the hardness of thermally aged Cu-Cr-Zr alloy[J]. Journal of Alloys and Compounds, 2009, 479(1/2): 303-306. [6] WANG Z, ZHONG Y, RAO X, et al.Electrical and mechanical properties of Cu-Cr-Zr alloy aged under imposed direct continuous current[J]. Transactions of Nonferrous Metals Society of China, 2012, 22(5): 1106-1111. [7] FU H, XU S, LI W, et al.Effect of rolling and aging processes on microstructure and properties of Cu-Cr-Zr alloy[J]. Materials Science and Engineering: A, 2017, 700: 107-115. [8] YE Y, YANG X, WANG J, et al.Enhanced strength and electrical conductivity of Cu-Zr-B alloy by double deformation- aging process[J]. Journal of Alloys and Compounds, 2014, 615: 249-254. [9] MISHNEV R, SHAKHOVA I, BELYAKOV A, et al.Deformation microstructures, strengthening mechanisms, and electrical conductivity in a Cu-Cr-Zr alloy[J]. Materials Science and Engineering A, 2015, 629: 29-40. [10] wZHANG S, LI R, KANG H, et al. A high strength and high electrical conductivity Cu-Cr-Zr alloy fabricated by cryorolling and intermediate aging treatment[J]. Materials Science and Engineering A, 2017, 680: 108-114. [11] LI R, ZHANG S, KANG H, et al.Microstructure and texture evolution in the cryorolled CuZr alloy[J]. Journal of Alloys and Compounds, 2017, 693: 592-600. [12] 王帅. Cu-0.69Cr-0.19Zr合金放电等离子烧结和热处理工艺研究[D]. 长沙: 中南大学, 2017. WANG Shuai.The study on spark plasma sintering and heat treatment of Cu-0.69Cr-0.19Zr alloy[D]. Changsha: Central South University, 2017. [13] HOYT J J.On the coarsening of precipitates located on grain boundaries and dislocations[J]. Acta Metallurgica et Materialia, 1991, 39(9): 2091-2098. [14] NAGARJUNA S, CHINTA BABU U, GHOSAL P.Effect of cryo-rolling on age hardening of Cu-1.5Ti alloy[J]. Materials Science and Engineering A, 2008, 491(1/2): 331-337. [15] KAPOOR K, LAHIRI D, BATRA I S, et al.X-ray diffraction line profile analysis for defect study in Cu-1wt.%Cr-0.1wt.%Zr alloy[J]. Materials Characterization, 2005, 54(2): 131-140. [16] SUN L X, TAO N R, LU K.A high strength and high electrical conductivity bulk CuCrZr alloy with nanotwins[J]. Scripta Materialia, 2015, 99: 73-76. [17] LU L, SHEN Y, CHEN X, et al.Ultrahigh strength and high electrical conductivity in copper[J]. Science, 2004, 304(5669): 422-426.