Abstract:To investigate the influence of layer thickness of iron powder on reducing efficiency in reducing furnace with H2 as reducing agent, the diffusion kinetic model of iron powder reduction was established using coupling kinetic model of FeO reduction and reducing gas oxidation. For 0.2 mm sponge iron powder with 0.74% remaining oxygen, the reduction condition is as follows: layer depth of 30 mm, heating time of 1 h,temperature of 850-900 ℃ and hydrogen flow of 30 Nm3/(t∙h). The remaining oxygen of product is 0.25%, which is coincidence with the calculation result (0.27%). The remaining oxygen in iron powder can be reduced easily. The hydrogen in the hydrogen reduction furnace penetrates into the iron powder layer, and the iron powder is reduced layer by layer from top to bottom. For 30 mm layer thickness, penetrating depth of hydrogen is about 25 mm, and another 5 mm thickness iron powder near the bottom can not be reduced. The remaining oxygen increases, the utilization rate of hydrogen and the yield decease with increasing layer thickness. When layer thickness decreases from 3 cm to 2 cm, reducing time will shorten 50%, yield will improve 33%, and consumption of H2 will decrease 50%.
郭培民, 赵沛, 孔令兵, 王磊. 料层厚度对粉末冶金用铁粉氢还原的影响[J]. 粉末冶金材料科学与工程, 2018, 23(3): 261-265.
GUO Peimin, ZHAO Pei, KONG Lingbing, WANG Lei. Effect of layer thickness on hydrogen reduction of iron powder in powder metallurgy. Materials Science and Engineering of Powder Metallurgy, 2018, 23(3): 261-265.
[1] 乐毅. 改善氢还原铁粉性能的研究[J]. 矿冶工程, 2007, 27(4): 35-38. YUE Yi.Process and parameter study aiming to improve the quality of hydrogen-reduced iron powder[J]. Mining and Metallurgical Engineering, 2007, 27(4): 35-38. [2] 李霆, 袁勇, 吕宝锋, 等. 用铁鳞制备低松比高细粉率还原铁粉试验[J]. 山东冶金, 2012, 34(4): 40-42, 45. LI Ting, YUAN Yong, LÜ Baofeng, et al.Test on preparing reduced iron powder with low apparent density and high fine powder rate by iron scale[J]. Shandong Metallurgy, 2012, 34(4): 40-42, 45. [3] 王崇琳, 张春光, 麻笑阳, 等. 铁精矿还原铁粉的质量稳定性[J]. 粉末冶金工业, 2012, 22(3): 7-15. WANG Chonglin, ZHANG Chunguang, MA Xiaoyang, et al.On the quality of iron powder reduced from iron ore concentrates[J]. Powder Metallurgy Industry, 2012, 22(3): 7-15. [4] 王世俊, 王克非, 乐可襄, 等. 二次精还原工艺对铁粉化学成分的影响[J]. 安徽工业大学学报, 2001, 18(2): 93-96. WANG Shijun, WANG Kefei, YUE Kexiang, et al.Effect of secondary reduction technology on chemical composition of iron powder[J]. J of Anhui University of Technology, 2001, 18(2): 93-96. [5] 韩凤麟. QMP公司水雾化铁粉与钢粉的生产[J]. 粉末冶金工业, 2003, 13(2): 16-21. HAN Fenglin.Production of atomized iron and steel powders at QMP CO[J]. Powder Metallurgy Industry, 2003, 13(2): 16-21. [6] 方建锋, 郭培民, 孔令兵, 等. 超纯铁精矿粉直接还原制备超细铁粉[J]. 粉末冶金材料科学与工程, 2016, 21(3): 421-426. FANG Jianfeng, GUO Peimin, KONG Lingbing, et al.Ultra-fine iron powder prepared by directly reducing super iron concentrates[J]. Materials Science and Engineering of Powder Metallurgy, 2016, 21(3): 421-426. [7] 庞建明, 郭培民, 赵沛, 等. 氢气还原氧化铁动力学的非等温热重方法研究[J]. 钢铁, 2009, 44(2): 11-14. PANG Jianming, GUO Peimin, ZHAO Pei, et al.Study on kinetics of gematite reduction by hydrogen at low temperature[J]. Iron and Steel, 2009, 44(2): 11-14. [8] 郭培民, 赵沛, 王磊, 等. 氧化铁气基还原过程的氧化动力学[J]. 钢铁, 2017, 52(9): 16-20. GUO Peimin, ZHAO Pei, WANG Lei, et al.Oxidizing kinetics of reducing gas during iron oxide reduction process[J]. Iron & Steel, 2017, 52(9): 16-20. [9] 郭培民, 赵沛, 王磊, 等. 工艺参数对移动床内氧化铁还原及还原气体氧化的影响[J]. 钢铁研究学报, 2018. 已接受. GUO Peimin, ZHAO Pei, WANG Lei, et al. Influence of technical parameters on reduction of iron ore and oxidation of reducing gas in moving bed[J]. Journal of Iron and Steel Research, 2018 (accepted).