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Effects of α-Al2O3 and silica sol strengthening treatment on the microstructure and performance of silica based ceramic cores |
PENG Yonghui1,2, ZHOU Wentao1,2, KOU Baohong1,2, OUYANG Jing1,2 |
1. Department of Inorganic Materials, School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China; 2. Hunan Key Laboratory of Mineral Materials and Application, Central South University, Changsha 410083, China |
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Abstract In this study, α-Al2O3 was selected as a mineralizer for the preparation of silica based ceramic cores used in precision casting. Techniques such as X-ray diffractometer, field emission scanning electron microscope, energy dispersive spectroscopy, and the three-point bending testing were employed to investigate the effects of mineralizer amount and silica sol strengthening treatment on the phase composition, microstructures, shrinkage rate, open porosity, density, and bending strength of the ceramic cores. The results indicate that α-Al2O3 exerts a dual effect on the ceramic cores. On one hand, it acts as a reinforcing phase that hinders the viscous flow of fused quartz and enhances the strength of the cores; on the other hand, its excellent high-temperature stability reduces the sintering density of the ceramic cores, leading to decreased shrinkage rates and strength. However, silica sol strengthening treatment effectively seals the pores and promotes sintering of the cores. After silica sol strengthening treatment, cores with w(α-Al2O3)=2% exhibit an increase in room temperature bending strength to 16.6 MPa and high-temperature bending strength to 37.5 MPa, meeting the application standards for ceramic cores in the precision casting industry.
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Received: 31 October 2024
Published: 15 April 2025
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[1] NIU S X, XU X Q, LI X, et al.Microstructure evolution and properties of silica-based ceramic cores reinforced by mullite fibers[J]. Journal of Alloys and Compounds, 2020, 829: 154494. [2] PAN Z P, GUO J Z, LI S M, et al.Experimental study on high temperature performances of silica-based ceramic core for single crystal turbine blades[J]. Ceramics International, 2022, 48(1): 548-555. [3] ZHANG J, WU J M, LIU H, et al.Infiltration of silica slurry into silica-based ceramic cores prepared by selective laser sintering based on pre-sintering[J]. Ceramics International, 2023, 49(19): 31477-31484. [4] FAN J X, XU X Q, NIU S X, et al.Anisotropy management on microstructure and mechanical property in 3D printing of silica-based ceramic cores[J]. Journal of the European Ceramic Society, 2022, 42(10): 4388-4395. [5] ZHENG W, WU J M, CHEN S, et al.Preparation of high-performance silica-based ceramic cores with B4C addition using selective laser sintering and SiO2-Al2O3 sol infiltration[J]. Ceramics International, 2023, 49(4): 6620-6629. [6] LI X, NIU S X, WANG D S, et al.Microstructure and crystallization kinetics of silica-based ceramic cores with enhanced high-temperature property[J]. Materials, 2023, 16(2): 606. [7] XI F S, ZHANG Z, WAN X H, et al.High-performance porous silicon/nanosilver anodes from industrial low-grade silicon for lithium-ion batteries[J]. ACS Applied Materials & Interfaces, 2020, 12(43): 49080-49089. [8] WANG J H, CHUNG C H, CHI P W, et al.Si@C core-shell nanostructure-based anode for Li-ion transport[J]. ACS Applied Nano Materials, 2023, 6(13): 12578-12587. [9] CHAE C, NOH H J, LEE J K, et al.A high-energy Li-ion battery using a silicon-based anode and a nano-structured layered composite cathode[J]. Advanced Functional Materials, 2014, 24(20): 3036-3042. [10] ZHANG Z Q, HUANG Y J, XIE Q Y, et al.Functional polymer-ceramic hybrid coatings: status, progress, and trend[J]. Progress in Polymer Science, 2024, 154: 101840. [11] ACKLEY B J, MARTIN K L, KEY T S, et al.Advances in the synthesis of preceramic polymers for the formation of silicon-based and ultrahigh-temperature non-oxide ceramics[J]. Chemical Reviews, 2023, 123(8): 4188-4236. [12] KAZEMI A, FAGHIHI-SANI M A, ALIZADEH H R. Investigation on cristobalite crystallization in silica-based ceramic cores for investment casting[J]. Journal of the European Ceramic Society, 2013, 33(15/16): 3397-3402. [13] NIU S X, LIU Z P, LUO Y S, et al.Reinforcement of silica-based ceramic cores based on amorphous and polycrystalline mullite fibers[J]. Ceramics International, 2023, 49(19): 31378-31384. [14] CHEN X, HAN J Q, ZHANG W, et al.Silica-based ceramic core for aviation applications: facile pore filling and flexural strength improvement[J]. International Journal of Applied Ceramic Technology, 2019, 16(6): 2181-2189. [15] LEE W E, JAYASEELAN D D, ZHANG S.Solid-liquid interactions: the key to microstructural evolution in ceramics[J]. Journal of the European Ceramic Society, 2008, 28(7): 1517-1525. [16] ZHANG B, YANG Y, FAN X L.Processing, microstructure, and properties of porous ceramic composites with directional channels[J]. Journal of Materials Science & Technology, 2024, 168: 1-15. [17] ZHANG X Y, CHENG X P, JANSOHN M, et al.t-ZrO2 toughened Al2O3 free-standing films and as oxidation mitigating thin films on silicon nitride via colloidal processing of flame made nanopowders(NPs)[J]. Journal of the American Ceramic Society, 2021, 104(3): 1281-1296. [18] EFTEKHARI A, MOVAHEDI B, DINI G, et al.Fabrication and microstructural characterization of the novel optical ceramic consisting of α-Al2O3@amorphous alumina nanocomposite core/shell structure[J]. Journal of the European Ceramic Society, 2018, 38(9): 3297-3304. [19] ZHAN L J, WU C Z, ZHANG F Q, et al.Coordinated regulation for α-Al2O3 and mullite structures in the alumina-mullite fiber based on the different adding form of Fe element[J]. Journal of the European Ceramic Society, 2024, 44(6): 4185-4195. [20] ZHENG W, WU J M, CHEN S, et al.Influence of Al2O3 content on mechanical properties of silica-based ceramic cores prepared by stereolithography[J]. Journal of Advanced Ceramics, 2021, 10(6): 1381-1388. |
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