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粉末冶金材料科学与工程  2023, Vol. 28 Issue (6): 565-579    DOI: 10.19976/j.cnki.43-1448/TF.2023055
  工艺技术 本期目录 | 过刊浏览 | 高级检索 |
C/SiC-ZrB2-TiB2复合材料的双相流烧蚀性能及抗烧蚀机制
章俭诚, 曾毅, 胡锦润, 李天佑, 王佳骏
中南大学 粉末冶金研究院,长沙 430081
Biphasic flow ablation properties and ablation resistance mechanisms of C/SiC-ZrB2-TiB2 composites
ZHANG Jiancheng, ZENG Yi, HU Jinrun, LI Tianyou, WANG Jiajun
Powder Metallurgy Research Institute, Central South University, Changsha 430081, China
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摘要 采用反应熔渗工艺制备C/SiC-ZrB2-TiB2复合材料,分别在单一等离子热流以及热流和粒子流相耦合的双相流烧蚀环境下,测试复合材料烧蚀性能,研究其抗烧蚀机制。结果表明:C/SiC-ZrB2-TiB2复合材料在两种热环境下均表现出优异的抗烧蚀性能。烧蚀温度为1 920 ℃和2 230 ℃时,复合材料在单一热流作用下的线烧蚀率分别为0.38 μm/s和19.80 μm/s,表面形成由ZrxTi1-xO2骨架和液态填充相组成的稳定氧化层,起到减缓烧蚀的作用。烧蚀温度为2 020 ℃和2 190 ℃时,复合材料在双相流作用下的线烧蚀率分别为2.93 μm/s和21.91 μm/s,SiC-ZrB2-TiB2陶瓷基体及其氧化层能在较高的温度下保持足够的强度,抵御粒子剥蚀,且碳纤维烧蚀程度较低,能起到较好的增强增韧效果。
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章俭诚
曾毅
胡锦润
李天佑
王佳骏
关键词 等离子热流粒子流烧蚀性能稳定氧化层剥蚀    
Abstract:The C/SiC-ZrB2-TiB2 composites were prepared by reactive melt infiltration process. The ablation properties of the composites were tested under a single plasma heat flow and a biphasic flow ablation environment in which the heat flow was coupled with the particle flow, respectively, and the ablation resistance mechanism of the composites was investigated. The results show that the C/SiC-ZrB2-TiB2 composites exhibit excellent ablation resistance in both thermal environments. The linear ablative rates of the composites are 0.38 μm/s and 19.80 μm/s under the action of single heat flow at ablation temperatures of 1 920 ℃ and 2 230 ℃, respectively, and a stable oxide layer consisting of ZrxTi1-xO2 skeleton and liquid filled phase is formed on the surface, which can slow down the ablation. The linear ablative rates of the composites under biphasic flow are 2.93 μm/s and 21.91 μm/s at ablation temperatures of 2 020 ℃ and 2 190 ℃, respectively. SiC-ZrB2-TiB2 ceramic matrix and its oxide layer can maintain sufficient strength at higher temperatures to resist particle exfoliation, and the carbon fibre ablation level is low, which can provide a better reinforcement and toughening effect.
Key wordsplasma heat flow    particle flow    ablation property    stable oxide layer    exfoliation
收稿日期: 2023-05-24      出版日期: 2024-01-23
ZTFLH:  TB332  
基金资助:国家自然科学基金资助项目(51602349)
通讯作者: 曾毅,教授,博士。电话:13786145568;E-mail: zengyi001@csu.edu.cn   
引用本文:   
章俭诚, 曾毅, 胡锦润, 李天佑, 王佳骏. C/SiC-ZrB2-TiB2复合材料的双相流烧蚀性能及抗烧蚀机制[J]. 粉末冶金材料科学与工程, 2023, 28(6): 565-579.
ZHANG Jiancheng, ZENG Yi, HU Jinrun, LI Tianyou, WANG Jiajun. Biphasic flow ablation properties and ablation resistance mechanisms of C/SiC-ZrB2-TiB2 composites. Materials Science and Engineering of Powder Metallurgy, 2023, 28(6): 565-579.
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