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Structure and mechanical properties of ordered graphene toughened zirconia ceramics prepared by tape casting |
CAI Weijin1,2, LI Qing1, LIU Yao1, LIU Shaojun1 |
1. Powder Metallurgy Research Institute, Central South University, Changsha 410083, China; 2. Shenzhen Research Institute, Central South University, Shenzhen 518057, China |
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Abstract Tetragonal zircona polycrysta (TZP) ceramics toughened by graphene nanosheets (GNS) were prepared by tape casting and spark plasma sintering. The effects of graphene content (volume fraction, the same below) on the phase composition, microstructure, hardness and fracture toughness of GNS/TZP ceramics were studied, and the toughening mechanism of ordered arrangement of graphene was further analyzed. The results show that,the addition of a small amount of graphene can significantly improve the fracture toughness of ceramics. The fracture toughness of zirconia ceramics with 0.25% graphene increases from 4.39 MPa·m0.5 to 7.21 MPa·m0.5, increased by 64.1%, and the hardness (HV20) decreases to 1 345.3, dcreased by less than 1%. The mechanism of toughening zirconia ceramics is mainly crack deflection and synergistic with various mechanisms.
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Received: 24 December 2020
Published: 19 June 2020
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[1] HANNINK R H, JELLY P, MUDDLE C.Transformation toughening in zirconia-containing ceramics[J]. Journal of the American Ceramic Society, 2000, 83(3): 461-487. [2] KELLY P, ROSE L.The martensitic transformation in ceramics-its role in transformation toughening[J]. Progress in Materials Science, 2002, 47(5): 463-557. [3] YOGH S D, CHOU C.Peculiar stress-induced phase transformation in YNbO4-modified ZrO2(3Y) using in situ compression-diffraction[J]. Materials Letters, 2002, 52(1): 69-74. [4] YEH T H, CHEN C, LEE H Y.Compression-induced reversible phase transformation with a cubic-like structure in 3mol.% yttria-stabilized zirconia[J]. Scripta Materialia, 2009, 61(10): 927-930. [5] TATARKO P, GRASSO, SALVATORE E, et al.Toughening effect of multi-walled boron nitride nanotubes and their influence on the sintering behaviour of 3Y-TZP zirconia ceramics[J]. Journal of the European Ceramic Society, 2014, 34(7): 1829-1843. [6] GEIM A K, NOVOSELOV K S.The rise of graphene[J]. Nature Materials, 2007, 6(3): 183-191. [7] SOLDANO C, ATHER M,ERIK D.Production, properties and potential of graphene[J]. Carbon, 2010, 48(8): 2127-2150. [8] MIRANZO P, BELMONTE M, OSENDI M.From bulk to cellular structures: A review on ceramic-graphene filler composites[J]. Journal of the European Ceramic Society, 2017: 83(3): 460-486. [9] PORWAL H, GRASSO, S, REECE M J.Review of grapheme- ceramic matrix composites[J]. Advances in Applied Ceramics, 2015, 112(8): 443-454. [10] ANDY N, ANKIT B, DEBRUPA L, et al.Graphene reinforced metal and ceramic matrix composites: A review[J]. Metallurgical Reviews, 2016, 62(5): 241-302. [11] CELIK Y, CELIK A, FLAHAUT E, et al.Anisotropic mechanical and functional properties of graphene-based alumina matrix nanocomposites[J]. Journal of the European Ceramic Society, 2016: 110(9): 439-450. [12] WALKER L S, MAROTTO M, Victoria R, et al.Toughening in graphene ceramic composites[J]. Acs Nano, 2011, 5(4): 3182-3190. [13] SHIN J H, HONG S H.Fabrication and properties of reduced graphene oxide reinforced yttria-stabilized zirconia composite ceramics[J]. Journal of the European Ceramic Society, 2014, 34(5):1297-1302. [14] SU J N, YAO C, HANG Q H.Graphene nanosheet-induced toughening of yttria-stabilized zirconia[J]. Applied Physics A, 2016, 123(1): 197-208. [15] TJONG S C.Recent progress in the development and properties of novel metal matrix nanocomposites reinforced with carbon nanotubes and graphene nanosheets[J]. Materials Science & Engineering Reports, 2013, 74(10): 281-350. [16] ZENG Y P.Preparation and properties of SiC whisker reinforced Al2O3 multiphase ceramics with directional arrangement[J]. Acta Silicate Sinica, 1998, 5(5): 558-564. [17] YASUHIRO G, AKKO T.Mechanical properties of unidirectionally orented SiC-whsker nored SiN, abdicated extrusion and hot-pressing[J]. American Ceramic Society, 1993: 76(6): 1420-1441. [18] TSAO I, DANFORTH S C.Inyecuon modable ceramic-ceramic compostes compounding behavior, whisker degradation and orentation[J]. Am Ceram Soc Bull, 1993: 72(2): 55-65. [19] HONG S H, MESSING G L.Development of textured mullite by templated grain growth[J]. Journal of the American Ceramic Society, 1999, 82(4): 867-872. [20] MORENO R.Colloidal processing of ceramics and composites[J]. Advances in Applied Ceramics, 2012, 111(5/6): 246-253. [21] NIIHARA K N, MORENA R, HASSELMAN D P H. Evaluation of KIC of brittle solids by the indentation method with low crack- to-indent ratios[J]. Journal of Materials Science Letters, 1982, 1(1): 13-16. [22] FERRARI A C, MEYER J C, SCARDACI V, et al.Raman spectrum of graphene and graphen layers[J]. Physical Review Letters, 2006, 97(18): 255-263. [23] NI Z H, WANG H M, Ma Y, et al.Tunable stress and controlled thickness modificatioin graphene by annealing[J]. ACS Nano, 2008, 2(5): 1033-1039. [24] DRESSELHAUS M S, JORIO A, HOFMANN M, et al.Perspectives on carbon nanotubes graphene Raman spectroscopy[J]. Nano letters, 2010, 10(3): 751-758. [25] KALBAC M, FARHAT H, KONG J, et al.Raman spectroscopy and in situ rar spectroelectrochemistry of bilayer 12C/13C graphene[J]. Nano Lett, 2011, 8(1): 742-753. [26] STEURER P, WISSERT R, THOMANN R, et al.Functionalized graphenes and thermoplastic nanocomposites based upon expanded graphite oxide[J]. Macromolecular Rapid Communications, 2009, 30(4/5): 316-327. [27] RAMIREZ A, CRISTINA, MARIA I.Toughening in ceramics containing graphene fillers[J]. Ceramics International, 40(7): 11187-11192. [28] OMELTCHENKO A, YU J, KALIA R K, et al.Crack front propagation and fracture in a graphite sheet: A molecular- dynamics study on parallel computers[J]. Physical Review Letters, 1997,78(11): 2148-2151. [29] LE M Q, BATRA R C.Single-edge crack growth in graphene sheets under tension[J]. Computational Materials Science, 2013, 69: 381-288. [30] 岳春光. 放电等离子烧结增强ZrB2基超高温陶瓷复合材料力学性能研究[D]. 苏州: 苏州大学, 2013. YUE Chunguang.Study on mechanical properties of ZrB2 based ultra-high temperature ceramic composites reinforced by discharge plasma sintering[D]. Suzhou: Soochow University, 2013. |
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