|
|
Effects of Ti(C0.7N0.3) addition on the microstructure and properties of (Ti,W,Ta)C-Mo-Ni cermets |
LIN Shaojiang1, CHEN Xiao2, XIONG Weihao2 |
1. School of Mechanical & Electrical Engineering of Hubei Polytechnic University, Huangshi 435003, China; 2. State Key Laboratory of Material Processing and Die & Mould Technology, Huazhong University of Science & Technology, Wuhan 430074, China |
|
|
Abstract The Ti(C,N)-based cermet materials were prepared by powder metallurgy using (Ti,W,Ta) C and Ti(C0.7N0.3) as hard phase materials. The effect of Ti(C0.7N0.3) additions on the microstructures and properties of (Ti,W,Ta)C-Mo-Ni cermets has been studied. The results indicate that the microstructure of (Ti,W,Ta)C-Mo-Ni cermets consist of black core-grey rim structure and white core-grey rim structure. The black cores is Ti(C0.7N0.3) particle and the white cores is (Ti,W,Ta)C particles. With increasing Ti(C0.7N0.3) addition, black cores increase and the rims become thinner. Adding Ti (C0.7N0.3) solid solution has little effect on the hardness of (Ti,W,Ta)C-Mo-Ni cermets, while the bending strength increases first and then decreases with the increase of Ti(C0.7N0.3). When the Ti(C0.7N0.3) content is 40%, the optimal properties of (Ti,W,Ta)C-Ti(C0.7N0.3)-Mo-Ni cermets is obtained, the hardness (HRA) is 90.3 and the bending strength is 1 748 MPa, respectively.
|
Received: 23 September 2019
Published: 19 June 2020
|
|
|
|
|
[1] 刘毅, 张鹛媚, 康希越, 等. w(Co)/w(Ni)对Ti(C,N)基金属陶瓷高温氧化和耐腐蚀性能的影响[J]. 粉末冶金材料科学与工程, 2019, 24(1): 27-36. LIU Yi, ZHANG Meimei, KANG Xiyue, et al.Effects of w(Co)/w(Ni) ratio on high-temperature oxidation and corrosion resistant behavior in Ti(C,N)-based cermets[J]. Materials Science and Engineering of Powder Metallurgy, 2019, 24(1): 27-36. [2] LIU Aijun, LIU Ning.Effect of granule size and WC content on microstructure and mechanical properties of double structure Ti(C,N) based cermets[J]. Rare Metal Materials and Engineering, 2019, 48(2): 375-384. [3] 马调调. Ti(C,N)基金属陶瓷性能影响因素及发展趋势[J]. 陶瓷, 2018(7): 20-27. MA Diaodiao.Influencing factors and development trend of Ti (C,N)-based cermets[J]. Ceramics, 2018(7): 20-27. [4] 肖水清, 刘杰, 肖白军, 等. 实现Ti(C,N)基金属陶瓷强韧化的技术路径[J]. 材料导报, 2018, 32(7): 1129-1138. XIAO Shuiqing, LIU Jie, XIAO Baijun, et al.Towards high-strength and high-toughness Ti(C,N)-based cermets: A technological review[J]. Materials Review, 2018, 32(7): 1129-1138. [5] KIEFFER R, ETTMAYER P.Modern Development in Powder Metallurgy[M]. New York: Plenum Press, 1971, 5: 201-203. [6] 许育东, 刘宁, 石敏, 等. 纳米改性Ti(C,N)基金属陶瓷研究进展[J]. 硬质合金, 2005, 22(2): 112-116. XU Yudong, LIU Ning, SHI Min, et al.Research progress of Ti(C,N) cermets with nano modification[J].Cemented Carbide, 2005, 22(2): 112-116. [7] 熊素建, 熊计, 郭智兴, 等. 纳米Ti(C,N)基金属陶瓷制备技术研究进展[J]. 硬质合金, 2009, 26(3): 194-200. XIONG Shuji, XIONG Ji, GUO Zhixing, et al.The process of research on the fabrication of nano-Ti(C,N)-based cermet[J]. Cemented Carbide, 2009, 26(3): 194-200. [8] NISHIMURA T, MURAYAMA K, KITADA T, et al.Some properties of cermet sintered in nitrogen gas[J]. International Journal Refractory Metals and Hard Materials, 1985; 35(1): 31-33. [9] AHN S Y, KANG S.Formation of core/rim structure in Ti(C,N)-WC-Ni cermets via a dissolution and precipitation process[J]. Journal of American Ceramic Society, 2000, 83(6): 1489-1494. [10] KIM S, MIN K, KANG S.Rim structure in Ti(C0.7N0.3)-WC-Ni cermets[J]. Journal of American Ceramic Society, 2003, 86(10): 1761-1766. [11] 李晨辉, 余立新, 熊惟皓. 硬质相粒度对金属陶瓷断裂韧性的影响[J]. 复合材料学报, 2003, 20(1): 1-6. LI Chenhui, YU Lixin, XIONG Weihao.Effect of hard phases grain size on cermets fracture toughness[J]. Acta Materiae Compositae Sinica, 2003, 20(1): 1-6. [12] 刘文俊, 熊惟皓, 郑勇. Ti(C,N)基金属陶瓷断口形貌及增韧机理[J]. 中国有色金属学报, 2006, 16(5): 800-804. LIU Wenjun, XIONG Weihao, ZHEN Yong.Appearance of fracture and toughening mechanisms of Ti(C,N)-based cermets[J]. The Chinese Journal of Nonferrous Metals, 2006, 16(5): 800-804. |
|
|
|