两步水热法制备纳米花状Ni3Fe/Ni3S2高效电催化剂促进碱性电解水析氧反应

doi:10.19976/j.cnki.43-1448/TF.2023039

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Abstract Ni₃Fe/Ni₃S₂ oxygen evolution catalysts were synthesized by two-step hydrothermal method using Fe(NO₃)₃·9H₂O and Na₂S·9H₂O as Fe source and S source, respectively, and nickel mesh (NM) as the Ni source and support substrate. The microstructure and morphology of the catalysts were analyzed by XRD, XPS, SEM, and TEM, and the electrochemical properties were tested by an electrochemical workstation. The results demonstrate that the Ni₃Fe/Ni₃S₂ catalyst synthesized by the two-step hydrothermal method has rich three-dimensional nanoflower morphology, which enhances the spatial utilization of the catalyst. Ni₃S₂ exposes a high refractive index $\{\bar{2}10\}$. crystalline surface, which contributes to the synergistic effect with the (111) crystalline surface of Ni₃Fe to enhance the catalytic activity. The oxygen evolution overpotential is 229 mV at a current density of 10 mA/cm² in 1 mol/L KOH (25 ℃), the overpotential is 335 mV for a current density of 600 mA/cm² in 5.35 mol/L KOH (80 ℃), and the decay rate of the overpotential is only 2.39% after 6 000 cyclic voltammetry cycles. It demonstrates that the catalyst has good oxygene evolution performance and stability.

Key words： oxygen evolution reaction transition metal sulfide hydrothermal Ni₃Fe/Ni₃S₂ electrocatalyst nickel mesh

Received: 31 March 2023 Published: 22 November 2023

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CHEN Yuxiang,HE Hanwei. Two-step hydrothermal preparing nanoflower-like Ni₃Fe/Ni₃S₂ high-efficiency electrocatalysts to enhance oxygen evolution reaction in alkaline media[J]. Materials Science and Engineering of Powder Metallurgy, 2023, 28(5): 427-437.

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http://pmbjb.csu.edu.cn/EN/10.19976/j.cnki.43-1448/TF.2023039 OR http://pmbjb.csu.edu.cn/EN/Y2023/V28/I5/427

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