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Modification of oil-wax-polypropylene based binder by EPDM for MIM |
ZHANG Chenming1, LU Renwei2, YANG Zhongchen2, LI Duxin1 |
1. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China; 2. Changsha Juzhong Metallurgy Technology Co. Ltd, Changsha 410000, China |
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Abstract EPDM was used as modifier in oil-wax-polypropylene based binder system for MIM in this paper. Four formulations of binder and 17-4PH stainless steel powder were mixed to prepare feedstocks and then injection molding. The effects of EPDM content on the rheological characteristics of feedstocks, properties of green parts as well as degreasing properties were studied. The results show that the viscosity of feedstock increases with EPDM addition. With the increase of EPDM content, the impact energy of green parts increases as well as bending strength decreases. The optimal mechanical properties of green parts are obtained when EPDM content is 2%. After seven cycles, the impact energy is 2.048 J, the bending strength is 6.3 MPa. In addition, the speed of solvent debinding increases with EPDM addition. Carbon content and oxygen content of debound parts can keep in reasonable range.
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Received: 29 March 2018
Published: 19 July 2019
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[1] 曲选辉. 粉末注射成形的研究进展[J]. 中国材料进展, 2010, 29(5): 42-47. QU Xuanhui.Research progress of powder injection molding[J]. Materials China, 2010, 29(5): 42-47. [2] 李笃信, 唐嵘, 李益民, 等. 金属粉末注射成形粘结剂及其研究进展[J]. 粉末冶金材料科学与工程, 1999, 4(4): 281-288. LI Duxin, TANG Rong, LI Yimin, et al.Metal powder injection molding binder and its research progress[J]. Materials Science and Engineering of Powder Metallurgy, 1999, 4(4): 281-288. [3] FU G, LOH N H, TOR S B, et al.Injection molding, debinding and sintering of 316L stainless steel microstructures[J]. Applied Physics A, 2005, 81(3): 495-500. [4] LI S, HUANG B, LI Y, et al.A new type of binder for metal injection molding[J]. Journal of Materials Processing Technology, 2003, 137(1/3): 70-73. [5] 范景莲, 黄伯云. 粘结剂组成对粘结剂和喂料热性能的影响[J]. 稀有金属材料与工程, 2004, 33(2): 213-217. FAN Jinglian, HUANG Baiyun.Effect of binder composition on binder properties and thermal properties of feedstock[J]. Rare Metal Materials and Engineering, 2004, 33(2): 213-217. [6] JANG J, LEE H, LEE W, et al. Evaluation of feedstock for powder injection molding[J]. Japanese Journal of Applied Physics, 2014, 53(5S3): 05HA03. [7] FAREH F, DEMERS V, DEMARQUETTE N R, et al.Influence of segregation on rheological properties of wax-based feedstocks[J]. Powder Technology, 2017, 320: 273-284. [8] 徐正伟, 李蕾, 徐灵明, 等. 石蜡油对三元乙丙橡胶硫化特性和动态性能的影响[J]. 合成橡胶工业, 2015, 38(4): 318-321. XU Zhengwei, LI Lei, XU Lingming, et al.Effect of paraffin oil on the vulcanization and dynamic properties of three ethylene propylene rubber[J]. China Synthetic Rubber Industry, 2015, 38(4): 318-321. [9] GERMAN R M, BOSE A.Injection Molding of Metals and Ceramics[M]. New Jersey: Metal Powder Industries Federation, 1997: 97-98. [10] 徐小明, 李笃信, 吴谓, 等. 改进型催化脱脂型粘结剂及其应用研究[J]. 粉末冶金工业, 2015, 25(5): 36-41. XU Xiaoming, LI Duxin, WU Wei, et al.The modified catalytic debinding binder and its application research[J]. Powder Metallurgy Industry, 2015, 25(5): 36-41. [11] 梁叔全, 黄伯云. 粉末注射成形流变学[M]. 长沙: 中南大学出版社, 2000: 35-36. LIANG Shuquan, HUANG Baiyun.Rheology of Powder Injection Molding[M]. Changsha: Central South University Press, 2000: 35-36. [12] ESCOBAR C F, SANTOS L A D. New eco-friendly binder based on natural rubber for ceramic injection molding process[J]. Journal of the European Ceramic Society, 2015, 35(13): 3567-3575. [13] RAMIREZ-VARGAS E, NAVARRO-RODRIGUEZ D, BLANQUETO-MENCHACA A I, et al. Degradation effects on the rheological and mechanical properties of multi-extruded blends of impact-modified polypropylene and poly (ethylene- co-vinyl acetate)[J]. Polymer Degradation & Stability, 2004, 86(2): 301-307. [14] AURREKOETXEA J, SARRIONANDIA M A, URRUTIB- EASCOA I, et al.Effects of recycling on the microstructure and the mechanical properties of isotactic polypropylene[J]. Journal of Materials Science, 2001, 36(11): 2607-2613. [15] 李铁, 田明, 隋军, 等. PP/EPDM共混合金的结构与性能研究[J]. 中国塑料, 2005, 19(1): 39-43. LI Tie, TIAN Ming, SUI Jun, et al.Study on the structure and properties of PP/EPDM blend[J]. China Plastics, 2005, 19(1): 39-43. [16] 张明轩. 聚烯烃类弹性体的特性及其对聚丙烯的增韧[D]. 浙江: 浙江大学, 2017: 26. ZHANG Mingxuan.Characteristics of polyolefin-based elastomers and their application in toughening modification of polypropylene[D]. Zhejiang: Zhejiang University, 2017: 26. [17] 王晓峰, 陈伟庆, 毕洪运, 等. 影响双相不锈钢热塑性的诸因素讨论[J]. 上海金属, 2007, 29(6): 37-41. WANG Xiaofeng, CHEN Weiqing, BI Hongyun, et al.Discussion on hot workability of duplex stainless steel[J]. Shanghai Metals, 2007, 29(6): 37-41. (编辑高海燕) |
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