|
|
Mechanical and ablation properties of 2D Cf-ZrB2-SiC composites prepared by slurry brushing-hot pressing method |
LI Tianyou, ZENG Yi, HU Jinrun, YI Bochao, GAO Meng |
Powder Metallurgy Research Institute, Central South University, Changsha 410083, China |
|
|
Abstract Continuous carbon fiber reinforced ZrB2-SiC composites have attracted much attention in the field of thermal protective structural materials for space vehicles due to their excellent oxidation and ablation resistance. In this paper, 2D Cf-ZrB2-SiC composites were prepared by the slurry brushing-hot pressing method, the feasibility of using micron-sized powder slurry to prepare 2D Cf-ZrB2-SiC composites was explored, the effects of sintering temperatures on the microstructure and mechanical properties of the materials were investigated, and the ablation resistance of the materials was tested. The results show that the 2D Cf-ZrB2-SiC composite prepared by micron-sized powder slurry brushing-hot pressing method has the highest density and flexural strength after sintering at 2 000 ℃, with an open porosity of 8.01% and a flexural strength of 191.3 MPa; it appears good ablation resistance, the surface response temperature reaches 2 600 ℃, and the linear ablation rate is 3.51 μm/s after plasma flame ablation for 300 s.
|
Received: 29 April 2024
Published: 30 September 2024
|
|
|
|
|
[1] NI D W, CHENG Y, ZHANG J P, et al.Advances in ultra-high temperature ceramics, composites, and coatings[J]. Journal of Advanced Ceramics, 2022, 11(1): 1-56. [2] 刘朋闯, 庞晓轩, 刘婷婷, 等. 热压烧结制备高密度ZrB2陶瓷[J]. 中国陶瓷, 2012, 48(5): 52-55. LIU Pengchuang, PANG Xiaoxuan, LIU Tingting, et al.Preparation of high density ZrB2 ceramics by hot-pressing[J]. China Ceramic,2012, 48(5): 52-55. [3] 程源. Cf/ZrC-SiC复合材料的强韧化与抗氧化性能研究[D].哈尔滨: 哈尔滨工业大学, 2020. CHENG Yuan.The study on strengthening-toughening and ablation-oxidation resistance of Cf/ZrC-SiC composities[D]. Harbin: Harbin Institute of Technology, 2020. [4] CHAMBERLAIN A L, FAHRENHOLTZ W G, HILMAS G E, et al.High-strength zirconium diboride-based ceramics[J]. Journal of the American Ceramic Society, 2004, 87(6): 1170-1172. [5] VERMA V, CHEVERIKIN V, CAMARACOZZA R.Review: effect on physical, mechanical, and wear performance of ZrB2‐based composites processed with or without additives[J]. International Journal of Applied Ceramic Technology, 2020, 17(6): 2509-2532. [6] SCITI D, MURRI A N, MEDRI V, et al.Continuous C fibre composites with a porous ZrB2 matrix[J]. Materials & Design, 2015, 85: 127-134. [7] ZUO F, CHENG L, XIANG L, et al.Ablative property of laminated ZrB2-SiC ceramics under oxyacetylene torch[J]. Ceramics International, 2013, 39(4): 4627-4631. [8] ZHANG X, CHEN Z K, XIONG X, et al.Morphology and microstructure of ZrB2-SiC ceramics after ablation at 3 000 ℃ by oxy-acetylene torch[J]. Ceramics International, 2016, 42(2): 2798-2805. [9] VINCI A, REIMER T, ZOLI L, et al.Influence of pressure on the oxidation resistance of carbon fiber reinforced ZrB2/SiC composites at 2 000 and 2 200 ℃[J]. Corrosion Science, 2021, 184: 109377. [10] YUTARO A, RYO I, KEN G, et al.Carbon fiber reinforced ultra-high temperature ceramic matrix composites: a review[J]. Ceramics International, 2019, 45(12): 14481-14489. [11] TANG S F, HU C L.Design, preparation and properties of carbon fiber reinforced ultra-high temperature ceramic composites for aerospace applications: a review[J]. Journal of Materials Science & Technology, 2017, 33(2): 117-130. [12] FAILLA S, GALIZIA P, ZOLI L, et al.Toughening effect of non-periodic fiber distribution on crack propagation energy of UHTC composites[J]. Journal of Alloys and Compounds, 2019, 777: 612-618. [13] PI H, FAN S, WANG Y.C/SiC-ZrB2-ZrC composites fabricated by reactive melt infiltration with ZrSi2 alloy[J]. Ceramic International, 2012, 38(8): 6541-6548. [14] NI D W, WANG J X, DONG S M, et al.Fabrication and properties of Cf-ZrC-SiC-based composites by an improved reactive melt infiltration[J]. Journal of the American Ceramic Society, 2018, 101(8): 3253-3258. [15] CHEN X W, NI D W, KAN Y, et al.Reaction mechanism and microstructure development of ZrSi2 melt-infiltrated Cf-SiC-ZrC-ZrB2 composites: the influence of preform pore structures[J]. Journal of Materiomics, 2018, 4(3): 266-275. [16] PATRA N, NASIRI N A, JAYASEELAN D D, et al.Thermal properties of Cf-HfC and Cf-HfC-SiC composites prepared by precursor infiltration and pyrolysis[J]. Journal of the European Ceramic Society, 2018, 38(5): 2297-2303. [17] LI Q G, DONG S M, WANG Z, et al.Fabrication and properties of 3D Cf-ZrB2-ZrC-SiC composites via polymer infiltration and pyrolysis[J]. Ceramics International, 2013, 39(5): 5937-5941. [18] ZOLI L, VINCI A, GALIZIA P, et al.Is spark plasma sintering suitable for the densification of continuous carbon fibre-UHTCMCs?[J]. Journal of the European Ceramic Society, 2020, 40(7): 2597-2603. [19] ZHANG D Y, HU P, DONG S, et al.Effect of pyrolytic carbon coating on the microstructure and fracture behavior of the Cf-ZrB2-SiC composite[J]. Ceramics International, 2018, 44(16): 19612-19618. [20] 汪长安, 王海龙, 王明福, 等. 二硼化锆超高温陶瓷的强韧化[J]. 硅酸盐学报, 2018, 46(12): 1653-1660. WANG Chang'an, WANG Hailong, WANG Mingfu, et al.Strengthening and toughening of zirconium diboride ultra-high temperature ceramics[J]. Journal of the Chinese Ceramic Society, 2018, 46(12): 1653-1660. [21] CHEN B W, NI D W, LIAO C J, et al.Long-term ablation behavior and mechanisms of 2D-Cf/ZrB2-SiC composites at temperatures up to 2 400 ℃[J]. Corrosion Science, 2020, 117: 108967. [22] 陈守刚, 尹衍升, 周春华, 等. 氧化锆相变稳定机制的研究进展及应用[J]. 硅酸盐通报, 2004, 3(19): 73-76. CHEN Shougang, YIN Yansheng, ZHOU Chunhua, et al.Application and study on the mechanism of the phase-stabilized zriconia[J]. Bulletin of the Chinese Ceramic Society, 2004, 3(19): 73-76. [23] CHEN B W, NI D W, LU J, et al.Multi-cycle and long-term ablation behavior of Cf/ZrB2-SiC composites at 2 500 ℃[J]. Corrosion Science, 2021, 184: 109385. [24] HU P, WANG G L, ZHI W.Oxidation mechanism and resistance of ZrB2-SiC composites[J]. Corrosion Science, 2009, 51(11): 2724-2732. |
|
|
|