统一外推模型与传统外推模型在Ag-Bi-Cu、In-Li-Sn和Al-Sn-Zn三元合金系混合焓计算中的性能对比

吕洋; 吕启文; 廖玲慧; 刘东云; 居天华

doi:10.19976/j.cnki.43-1448/TF.2024120

粉末冶金材料科学与工程 >

2025 , Vol. 30 >Issue 3: 193 - 203

DOI: https://doi.org/10.19976/j.cnki.43-1448/TF.2024120

理论研究

统一外推模型与传统外推模型在Ag-Bi-Cu、In-Li-Sn和Al-Sn-Zn三元合金系混合焓计算中的性能对比

吕洋 ,
吕启文 ,
廖玲慧 ,
刘东云 ,
居天华

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1.广西大学资源环境与材料学院,南宁 530004;
2.广西大学广西高校高性能结构材料及热表加工重点实验室,南宁 530004;
3.广西大学省部共建特色金属材料与组合结构全寿命安全国家重点实验室,南宁 530004

居天华,助理教授,博士。电话：18642084587;E-mail: jutianhua@gxu.edu.cn

收稿日期: 2024-12-31

修回日期: 2025-06-06

网络出版日期: 2025-07-28

基金资助

广西科技基地和人才专项资助项目(AD23026259)

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Performance comparison of unified and traditional extrapolation models in calculating enthalpy of mixing of Ag-Bi-Cu, In-Li-Sn, and Al-Sn-Zn ternary alloy systems

LÜ Yang ,
LÜ Qiwen ,
LIAO Linghui ,
LIU Dongyun ,
JU Tianhua

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1. School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China;
2. Key Laboratory of High Performance Structural Materials and Thermo-Surface Processing, Guangxi University, Nanning 530004, China;
3. State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures,Guangxi University, Nanning, 530004, China

Received date: 2024-12-31

Revised date: 2025-06-06

Online published: 2025-07-28

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摘要

合金溶液的热力学性质是评估合金相稳定性及计算相图的重要数据,准确预测这些数据对开发新合金材料、优化冶金过程、提高产品质量和降低生产成本具有重要意义。本文利用统一外推模型(unified extrapolation model, UEM)计算了Ag-Bi-Cu、In-Li-Sn和Al-Sn-Zn三元合金系在不同组成下的混合焓,并与多种常用的外推模型(Kohler、Muggianu、Toop和通用溶液模型)的计算结果以及文献中的实验数据进行对比。结果表明,UEM的预测结果整体上优于其他模型,在热力学性质预测方面表现出较高的准确性和适用性。

关键词： 多元合金溶液; 热力学模型; 外推模型; 热力学性质; 混合焓

本文引用格式

吕洋 , 吕启文 , 廖玲慧 , 刘东云 , 居天华 . 统一外推模型与传统外推模型在Ag-Bi-Cu、In-Li-Sn和Al-Sn-Zn三元合金系混合焓计算中的性能对比[J]. 粉末冶金材料科学与工程, 2025 , 30(3) : 193 -203 . DOI: 10.19976/j.cnki.43-1448/TF.2024120

Abstract

The thermodynamic properties of alloy solutions are crucial for evaluating phase stability and calculating phase diagrams. Accurate prediction of these data is of great significance for the development of new alloy materials, optimization of metallurgical processes, improvement of product quality, and reduction of production costs. In this study, the unified extrapolation model (UEM) was employed to calculate the enthalpy of mixing of the Ag-Bi-Cu, In-Li-Sn, and Al-Sn-Zn ternary alloy systems at various compositions. The results were compared with those obtained from several commonly used extrapolation models, including the Kohler, Muggianu, Toop, and general solution models, as well as experimental data reported in the literatures. The findings indicate that UEM provides overall superior predictions compared to other models, demonstrating higher accuracy and applicability in the prediction of thermodynamic properties.

Key words： multicomponent alloy solution; thermodynamic model; extrapolation model; thermodynamic property; enthalpy of mixing

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