电沉积法制备自支撑Ni-Sn-B电极的显微结构与电催化析氢性能

阳刚; 何捍卫

doi:10.19976/j.cnki.43-1448/TF.2023031

粉末冶金材料科学与工程 >

2023 , Vol. 28 >Issue 3: 276 - 287

DOI: https://doi.org/10.19976/j.cnki.43-1448/TF.2023031

工艺技术

电沉积法制备自支撑Ni-Sn-B电极的显微结构与电催化析氢性能

阳刚 ,
何捍卫

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中南大学粉末冶金研究院,长沙 410083

收稿日期: 2023-03-27

修回日期: 2023-05-09

网络出版日期: 2023-07-06

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Microstructure and electrocatalytic hydrogen evolution performance of self-supported Ni-Sn-B electrode prepared by electrodeposition method

YANG Gang ,
HE Hanwei

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Powder Metallurgy Research Institute, Central South University, Changsha 410083, China

Received date: 2023-03-27

Revised date: 2023-05-09

Online published: 2023-07-06

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摘要

为开发高效稳定的析氢电催化剂,采用恒电流电沉积法在镍网基底上制备自支撑的Ni-Sn-B析氢电极,通过扫描电镜、X射线衍射仪、透射电镜、X射线光电子能谱仪和电化学工作站等对电极的形貌结构、元素组成与电催化析氢性能进行表征和测试。结果表明,Ni-Sn-B电极表面由粗糙的胞状颗粒紧密堆积而成,具有非晶态特征结构。在碱性电解质中,Ni-Sn-B电极表现出优异的催化析氢活性和稳定性,在10 mA/cm²电流密度下过电位仅为63 mV,比Ni-Sn和Ni-B电极的过电位分别降低38.2%和59.1%。电极的电荷转移电阻为1.56 Ω,经过5 000次CV循环和72 h电解后,仍保持非常高的析氢活性。粗糙的表面形貌及非晶态结构使电极的电化学活性表面积和催化活性位点显著增加,同时B和Sn对Ni电子结构的调控,可有效降低电荷转移阻力,从而提升电极的电催化析氢性能。

关键词： Ni-Sn-B电催化剂; 电沉积; 自支撑电极; 析氢反应; 镍网

本文引用格式

阳刚 , 何捍卫 . 电沉积法制备自支撑Ni-Sn-B电极的显微结构与电催化析氢性能[J]. 粉末冶金材料科学与工程, 2023 , 28(3) : 276 -287 . DOI: 10.19976/j.cnki.43-1448/TF.2023031

Abstract

To develop efficient and stable hydrogen evolution electrocatalysts, Ni-Sn-B hydrogen evolution electrode were prepared on Ni mesh substrate by galvanostatic electrodeposition method. The morphology, structure, elemental composition, and electrocatalytic hydrogen evolution properties of the electrode were characterized and tested by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and electrochemical workstation. The results show that the surface of Ni-Sn-B electrode is composed of rough cellular particles, which are closely packed and have amorphous characteristic structure. Ni-Sn-B electrode has excellent catalytic performance and stability for hydrogen evolution in alkaline solution. The overpotential is only 63 mV at current density of 10 mA/cm², which is 38.2% and 59.1% lower than that of Ni-Sn and Ni-B electrodes. The charge transfer resistance of electrode is 1.56 Ω, and the excellent hydrogen evolution activity is still maintained after 5 000 cycles of voltammetry and 72 h electrolysis. The abundant surface morphology and amorphous characteristic structure can significantly increase the electrochemical active surface area and catalytic active site. The regulation of B and Sn on the electronic structure of Ni effectively decreases the charge transfer resistance and improves the properties of electrocatalytic hydrogen evolution reaction.

Key words： Ni-Sn-B electrocatalyst; electrodeposition; self-supported electrode; hydrogen evolution reaction; Ni mesh

参考文献

[1] LI Y J, SUN Y J, QIN Y N, et al.Recent advances on water- splitting electrocatalysis mediated by noble-metal-based nanostructured materials[J]. Advanced Energy Materials, 2020, 10(11): 1903120.
[2] WU Y H, LIAN J Q, WANG Y X, et al.Potentiostatic electrodeposition of self-supported Ni-S electrocatalyst supported on Ni foam for efficient hydrogen evolution[J]. Materials & Design, 2021, 198: 109316.
[3] CHEN W W, MISHRA I K, QIN Z J, et al.Nickel phosphide based hydrogen producing catalyst with low overpotential and stability at high current density[J]. Electrochimica Acta, 2019, 299: 756-761.
[4] ANANTHARAJ S, NODA S, JOTHI V R, et al.Strategies and perspectives to catch the missing pieces in energy-efficient hydrogen evolution reaction in alkaline media[J]. Angewandte Chemie International Edition, 2021, 60(35): 18981-19006.
[5] ENSAFI A A, ZANDI-ATASHBAR N, MOHAMADI Z, et al.Pt-Pd nanoparticles decorated sulfonated graphene-poly (3, 4-ethylene dioxythiophene) nanocomposite, an efficient HER electrocatalyst[J]. Energy, 2017, 126: 88-96.
[6] BREWER L.Bonding and structures of transition metals: spectroscopy of gaseous atoms provides predictions of structures and thermodynamic properties of metals[J]. Science, 1968, 161(3837): 115-122.
[7] SAFIZADEH F, GHALI E, HOULACHI G.Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions: a review[J]. International Journal of Hydrogen Energy, 2015, 40(1): 256-274.
[8] JI Z J, LIU J, DENG Y, et al.Accurate synergy effect of Ni-Sn dual active sites enhances electrocatalytic oxidation of urea for hydrogen evolution in alkaline medium[J]. Journal of Materials Chemistry A, 2020, 8(29): 14680-14689.
[9] ZHU Y B, ZHANG X H, SONG J L, et al.Microstructure and hydrogen evolution catalytic properties of Ni-Sn alloys prepared by electrodeposition method[J]. Applied Catalysis A: General, 2015, 500: 51-57.
[10] ZHU Y B, LIU T, LI L M, et al.Nickel-based electrodes as catalysts for hydrogen evolution reaction in alkaline media[J]. Ionics, 2018, 24(4): 1121-1127.
[11] YAMASHITA H, YAMAMURA T, YOSHIMOTO K.The relation between catalytic ability for hydrogen evolution reaction and characteristics of nickel‐tin alloys[J]. Journal of the Electrochemical Society, 1993, 140(8): 2238-2243.
[12] LIU Y C, LU H X, KOU X L.Electrodeposited Ni-Co-Sn alloy as a highly efficient electrocatalyst for water splitting[J]. International Journal of Hydrogen Energy, 2019, 44(16): 8099-8108.
[13] LU S Y, LI S W, JIN M, et al.Greatly boosting electrochemical hydrogen evolution reaction over Ni₃S₂ nanosheets rationally decorated by Ni₃Sn₂S₂ quantum dots[J]. Applied Catalysis B: Environmental, 2020, 267: 118675.
[14] LIU F, HE W J, LI Y, et al.Activating sulfur sites of CoS₂ electrocatalysts through tin doping for hydrogen evolution reaction[J]. Applied Surface Science, 2021, 546: 149101.
[15] HUANG T, SHEN T, GONG M X, et al.Ultrafine Ni-B nanoparticles for efficient hydrogen evolution reaction[J]. Chinese Journal of Catalysis, 2019, 40(12): 1867-1873.
[16] ZHANG P L, WANG M, YANG Y, et al.Electroless plated Ni-B_x films as highly active electrocatalysts for hydrogen production from water over a wide pH range[J]. Nano Energy, 2016, 19: 98-107.
[17] YUSUF B A, XU Y G, ULLAH N, et al.B-doped carbon enclosed Ni nanoparticles: a robust, stable and efficient electrocatalyst for hydrogen evolution reaction[J]. Journal of Electroanalytical Chemistry, 2020, 869: 114085.
[18] ZHANG R Q, LIU H X, WANG C F, et al.Electroless plating of transition metal boride with high boron content as superior HER electrocatalyst[J]. ChemCatChem, 2020, 12(11): 3068-3075.
[19] WANG S J, ZOU X L, LU Y, et al.Electrodeposition of nano-nickel in deep eutectic solvents for hydrogen evolution reaction in alkaline solution[J]. International Journal of Hydrogen Energy, 2018, 43(33): 15673-15686.
[20] KADIER A, SIMAYI Y, CHANDRASEKHAR K, et al.Hydrogen gas production with an electroformed Ni mesh cathode catalysts in a single-chamber microbial electrolysis cell (MEC)[J]. International Journal of Hydrogen Energy, 2015, 40(41): 14095-14103.
[21] SUN S F, SUN G P, CHENG P F, et al.iRs-corrections induce potentially misjudging toward electrocatalytic water oxidation[J]. Materials Today Energy, 2023, 32: 101246.
[22] LIU W, TAN W Y, YANG Y, et al.One-step galvanostatic electrodeposition of Ni-Se-Dy film on Ni foam for hydrogen evolution reaction in alkaline solution[J]. Journal of Alloys and Compounds, 2022, 925: 166706.
[23] ZHANG H, LI F J, JI S, et al.One-step electrodeposition of cauliflower-like Ni-Fe-Sn particles as a highly-efficient electrocatalyst for the hydrogen evolution reaction[J]. International Journal of Hydrogen Energy, 2020, 45(46): 24615-24625.
[24] XU X S, DENG Y X, GU M H, et al.Large-scale synthesis of porous nickel boride for robust hydrogen evolution reaction electrocatalyst[J]. Applied Surface Science, 2019, 470: 591-595.
[25] SHENG M Q, WU Q, WANG Y, et al.Network-like porous Co-Ni-B grown on carbon cloth as efficient and stable catalytic electrodes for hydrogen evolution[J]. Electrochemistry Communications, 2018, 93: 104-108.
[26] ZHANG Y, YE F, LI W D Z. Self-assembled two- dimensional NiO/CeO₂ heterostructure rich in oxygen vacancies as efficient bifunctional electrocatalyst for alkaline hydrogen evolution and oxygen evolution[J]. Chemistry A: European Journal, 2021, 27(11): 3766-3771.
[27] LIU C C, HU Y C, LIU F, et al.Electronic structure modulation of CoSe₂ nanowire arrays by tin doping toward efficient hydrogen evolution[J]. International Journal of Hydrogen Energy, 2021, 46(33): 17133-17142.
[28] ZHANG L, WEI K, MA J M, et al.Coupled Sn/Mo₂C nanoparticles wrapped in carbon nanofibers by electrospinning as high-performance electrocatalyst for hydrogen evolution reaction[J]. Applied Surface Science, 2021, 566: 150754.
[29] SARKAR S, PETER S C.Dealloying induced manipulative disruption of Ni₂P-SnP heterostructure enabling enhanced hydrogen evolution reaction[J]. The Journal of Physical Chemistry C, 2021, 125(24): 13225-13233.
[30] SARAVANAKUMAR T, SELVARAJU T, BHOJANAA K B, et al.Exploring the synergistic effect of Ni_xSn₂_xS₄_x thiospinel with MWCNTs for enhanced performance in dye-sensitized solar cells, the hydrogen evolution reaction, and supercapacitors[J]. Dalton Transactions, 2020, 49(16): 5336-5351.
[31] LIU W, TAN W Y, HE H W, et al.Electrodeposition of self-supported Ni-Mg-La electrocatalyst on Ni foam for efficient hydrogen evolution reaction[J]. Electrochimica Acta, 2022, 411: 140058.
[32] FENG W S, PANG W B, XU Y, et al.Transition metal selenides for electrocatalytic hydrogen evolution reaction[J]. ChemElectroChem, 2020, 7(1): 31-54.

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