磁响应光子晶体四氧化三铁的制备及磁致变色

田兆霞; 吴志生; 肖威; 许高杰; 刘丰华

doi:10.19976/j.cnki.43-1448/TF.2023001

粉末冶金材料科学与工程 >

2023 , Vol. 28 >Issue 2: 129 - 140

DOI: https://doi.org/10.19976/j.cnki.43-1448/TF.2023001

工艺技术

磁响应光子晶体四氧化三铁的制备及磁致变色

田兆霞 ,
吴志生 ,
肖威 ,
许高杰 ,
刘丰华

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1.太原科技大学材料科学与工程学院,太原 030024;
2.中国科学院宁波材料技术与工程研究所,浙江省增材制造材料重点实验室,宁波 315201

收稿日期: 2023-01-01

修回日期: 2023-02-10

网络出版日期: 2023-05-04

基金资助

江苏省产业前瞻与关键核心技术项目(BE2019072); 甘肃省技术创新引导计划区域科技合作专项(20JR10QA579)

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Preparation and magnetochromic discoloration of ferroferric oxide magnetically responsive photonic crystals

TIAN Zhaoxia ,
WU Zhisheng ,
XIAO Wei ,
XU Gaojie ,
LIU Fenghua

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1. School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China;
2. Zhejiang Key Laboratory of Additive Manufacturing Materials, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China

Received date: 2023-01-01

Revised date: 2023-02-10

Online published: 2023-05-04

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摘要

用三氯化铁(FeCl₃)提供铁源,分别以2种不同化学结构的聚(4-苯乙烯磺酸-共聚-马来酸)(poly styrene sulfonic acid-co-maleic acid PSSMA)钠盐作为表面活性剂,采用溶剂热法制备磁响应四氧化三铁(Fe₃O₄)纳米颗粒。研究不同结构的PSSMA表面活性剂和反应条件对Fe₃O₄纳米颗粒形貌、粒径与光学性能的影响。结果表明,在强碱环境下,以n(SS)∶n(MA)=1∶1的PSSMA作表面活性剂制备的Fe₃O₄粒子表面粗糙,为近球形,粒径随水量增加而增大;在弱碱条件下,以n(SS)∶n(MA)=3∶1的PSSMA为表面活性剂制备的Fe₃O₄粒子表面光滑,为规则球形,粒径随Fe³⁺含量增加而增大。在弱碱环境下,由于PSSMA(3∶1)表面含有更丰富的磺酸基,更适合生成粒径均一、单分散性好且具有优异超顺磁性的Fe₃O₄纳米颗粒。该Fe₃O₄纳米颗粒分散体系在外磁场作用下可快速形成有序光子晶体纳米颗粒群,获得优异的可调结构色。

关键词： 磁响应光子晶体; 四氧化三铁; PSSMA; 粒径; 磁致变色

本文引用格式

田兆霞 , 吴志生 , 肖威 , 许高杰 , 刘丰华 . 磁响应光子晶体四氧化三铁的制备及磁致变色[J]. 粉末冶金材料科学与工程, 2023 , 28(2) : 129 -140 . DOI: 10.19976/j.cnki.43-1448/TF.2023001

Abstract

Magnetically responsive ferroferric oxide (Fe₃O₄) nanoparticles were prepared by solvothermal method using ferric trichoride (FeCl₃) as the iron source and poly (styrene sulfonic acid-co-maleic acid) (PSSMA) sodium salt with two different chemical structures as surfactants. The effects of PSSMA surfactants with different structures and reaction conditions on the morphology, particle size, and photonic properties of Fe₃O₄nanoparticles were investigated. The results show that the Fe₃O₄particles are nearly spherical and surface is rough when using PSSMA with n(SS)∶n(MA)=1∶1 as surfactant in strong alkali environment, and particle size increases with increasing water content. Using PSSMA with n(SS)∶n(MA)=3∶1 as surfactant in weak alkali environment, the particles are regular spherical and surface is smooth, and the size increases with increasing Fe³⁺ content. It is more suitable for the generation of superparamagnetic Fe₃O₄ nanoparticles with uniform particle size and good monodispersity in weak alkaline environment due to the more abundant sulfonic acid group on the surface. This Fe₃O₄ nanoparticle dispersion system can rapidly form ordered photonic crystal nanoparticles under the action of external magnetic field, and obtain excellent tunable structure color.

Key words： magnetically responsive photonic crystals; ferroferric oxide; PSSMA; particle size; magnetic discoloration

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