|
|
Effect of powder loading on mechanical properties of metal injection molding 17-4PH stainless steel |
YU Jian1,2, LI Yimin1,2, LI Dongyang2, LI Xing2 |
1. Hunan Injection High Technology Co., Ltd, Changsha 410083, China; 2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China |
|
|
Abstract The binder composition POM (polyformaldehyde) in the injection molded 17-4PH stainless steel body was catalytically degreased under nitric acid atmosphere, and then thermal degreasing and sintering were carried out in a vacuum sintering furnace. The effects of powder loading and catalytic degreasing time on the catalytic degreasing rate were studied, and the effects of powder loading on the microstructure, density and tensile strength of sintered products were also studied. The results show that the microstructure of the sintered products is composed of austenite and a small amount of ferrite. With increasing the powder loading from 55.1% to 65.7%, the catalytic degreasing rate of the sintered sample decreases from 7.8% to 5.2%; the density increases from 7.56 g/cm3 to 7.66 g/cm3, and the tensile strength increases from 1 076 MPa to 1 204 MPa. With increasing the thermal retention time from 30 min to 90 min at 130 ℃, the catalytic degreasing rate increases from 4.9% to 6.7%. When the thermal retention time in the range of 90-150 min, the catalytic degreasing rate stabilise at about 6.7%. With the powder loading of 65.7%, the POM in the binder can be completely removed by 90min catalytic degreasing. The degreasing rate reaches 87%, and the injection blank forms a complete communicating channel.
|
Received: 17 March 2017
Published: 11 July 2019
|
|
|
|
|
[1] 杨忠臣. 17-4PH不锈钢粉末注射成形工艺研究[D]. 长沙: 中南大学, 2013. YANG Zhongchen.Research on powder injection molding of 17-4PH stainless steel[D]. Changsha: Central South University, 2013. [2] 李益民, KHALIL K A, 黄伯云. 金属注射成形17-4PH不锈钢脱脂保形性研究[J]. 稀有金属材料与工程, 2005, 34(1): 22-27. LI Yimin, KHALIL K A, HUANG Bayun.Compact shape retention for metal injection molding 17-4PH stainless steel[J]. Rare Metal Materials and Engineering, 2005, 34(1): 22-27. [3] JUN Wang, LIN Yuanhua, ZENG Dezhi, et al.Effects of the process parameters on the microstructure and properties of Nitrided 17-4PH stainless steel[J]. Metallurgical and Materials Transactions B, 2013, 44(2): 414-422. [4] 杜大明, 汪洋, 白小波. 热处理对17-4PH不锈钢组织和性能的影响[J]. 热处理技术与装备, 2012, 33(1): 30-32. DU Daming, WANG Yang, BAI Xiaobo.Effect of heat treatment on microstructure and property of 17-4PH stainless steel[J]. Heat Treatment Technology and Equipment, 2012, 33(1): 30-32. [5] 邓德伟, 陈蕊, 田鑫, 等. 热处理对17-4PH马氏体不锈钢显微组织及性能的影响[J]. 金属热处理, 2013, 38(4): 32-36. DENG Dewei, CHEN Rui, TIAN Xin, et al.Influence of heat treatment on microstructure and properties of 17-4PH martensitic stainless steel[J]. Heat Treatment of Metals, 2013, 38(4): 32-36. [6] LI Yimin, KHALIL K A, HUANG Boyun.Rheological, mechanical and corrosive properties of injection molded 17-4PH stainless steel[J]. Chinese Journal of Nonferrous Metals, 2004, 14(5): 934-939. [7] BLEOMACHER M T P. BASF extends scope of its MIM process[J]. Metal Powder Report, 1994, 49(9): 20-21. [8] BLOEMACHER M.Acetyl based feedstock for injection moulding and catalytic debinding[J]. Metal Powder Report, 1998, 53(1): 40. [9] 张翔, 何浩, 李益民, 等. 碳含量对金属注射成形17-4PH不锈钢显微组织和力学性能的影响[J]. 中国有色金属学报, 2015(4): 945-951. ZHANG Xiang, HE Hao, LI Yimin, et al.Effect of carbon content on microstructure and mechanical properties of metal injection molded 17-4PH stainless steel[J]. The Chinese Journal of Nonferrous Metals, 2015(4): 945-951. [10] WU Yunxin, GERMAN R M, BLAINE D, et al.Effects of residual carbon content on sintering shrinkage, microstructure and mechanical properties of injection molded 17-4 PH stainless steel[J]. Journal of Materials Science, 2002, 37(17): 3573-3583. |
|
|
|