|
|
Optimization of process parameters for selective laser melting of Cu-Cr-Nb alloy |
REN Yake1, LIU Zuming1, ZHANG Yazhou1, AI Yongkang1, YE Shupeng1, LI Jian1, PENG Weicai2 |
1. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China; 2. Changsha Mitr Instrument Equipment Co., Ltd., Changsha 410219, China |
|
|
Abstract Cu-1.93Cr-0.74Nb (mole fraction, %) alloy was prepared by selective laser melting (SLM) using Ar-gas atomized powders. The effects of laser power, scanning speed and scanning spacing on the relative density, molten pool morphology, and microstructure of as-built samples were investigated. The results show that the effects of SLM process parameters on the relative density, metallurgical defects and microstructure of as-built Cu-1.93Cr-0.74Nb alloy are nonlinear. The relative density of as-built sample increases first and then decreases with increasing the laser power from 300 W to 400 W, or the scanning speed from 500 mm/s to 1 100 mm/s. The number and size of pore also shows a similar change rule. The relative density is closely related to the continuity of melting pool, the number and size of pore. The relative density of as-built Cu-1.93Cr-0.74Nb alloy prepared by optimum parameters of the laser power of 330 W, the scanning speed of 800 mm/s and the scanning space of 0.1 mm, reaches 99.3%. It has a bimodal core-shell structure and a strong {110} texture with a large-sized grain as the center and fine grains distributed on the shell. The texture index and texture strength are 9.319 and 7.812, respectively.
|
Received: 02 June 2021
Published: 28 February 2022
|
|
|
|
|
[1] TENWICK M J, DAVIES H A.Enhanced strength in high conductivity copper alloys[J]. Materials Science and Engineering A, 1988, 98: 543-546. [2] CHOI J H.Aging behavior and precipitate analysis of copper-rich Cu-Fe-Mn-P alloy[J]. Materials Science and Engineering A, 2012, 550:183-190. [3] KIM H G, HAN S Z, EUH K, et al.Effects of C addition and thermo-mechanical treatments on microstructures and properties of Cu-Fe-P alloys[J]. Materials Science and Engineering A, 2011, 530: 652-658. [4] FU H, XU S, LI W, et al.Effect of rolling and aging processes on microstructure and properties of Cu-Cr-Zr alloy[J]. Materials Science and Engineering A, 2017, 700: 107-115. [5] 赵凡, 刘祖铭, 吕学谦, 等. 粉末冶金Cu-Cr-Zr合金的形变热处理组织及性能[J]. 粉末冶金材料科学与工程, 2019, 24(4): 385-390. ZHAO Fan, LIU Zuming, LÜ Xueqian, et al.Microstructure and properties of powder metallurgical Cu-Cr-Zr alloy by heat-treatment and deformation[J]. Materials Science and Engineering of Powder Metallurgy, 2019, 24(4): 385-390. [6] LEI Q, LI Z, DAI C, et al.Effect of aluminum on microstructure and property of Cu-Ni-Si alloys[J]. Materials Science and Engineering A, 2013, 572: 65-74. [7] WANG W, KANG H, CHEN Z, et al.Effects of Cr and Zr additions on microstructure and properties of Cu-Ni-Si alloys[J]. Materials Science and Engineering A, 2016, 673: 378-390. [8] JANOVSZKY D, TOMOLYA K, SVEDA M, et al.Effect of Y and Ni addition on liquid immiscibility in Cu-Zr-Ag ternary alloys[J]. Journal of Alloys and Compounds, 2014, 615: S616-S620. [9] LI H, JIE J, CHEN H, et al.Effect of rotating magnetic field on the microstructure and properties of Cu-Ag-Zr alloy[J]. Materials Science and Engineering A, 2015, 624: 140-147. [10] DEGROH H C, ELLIS D L, LOEWENTHAL W S.Comparison of grcop-84 to other Cu alloys with high thermal conductivities[J]. Journal of Materials Engineering and Performance, 2007, 17(4): 594-606. [11] SHUKLA A K, SHARMA V M J, MURTY S V S N, et al. Integrity of structural and thermo-structural materials for indian space programme[J]. Procedia Engineering, 2014, 86: 8-17. [12] DENG H, YI J, XIA C, et al.Mechanical properties and microstructure characterization of well-dispersed carbon nanotubes reinforced copper matrix composites[J]. Journal of Alloys and Compounds, 2017, 727: 260-268. [13] REN S, CHEN J, HE X, et al.Effect of matrix-alloying-element chromium on the microstructure and properties of graphite flakes/copper composites fabricated by hot pressing sintering[J]. Carbon, 2018, 127: 412-423. [14] 彭刚, 蔡晓兰, 周蕾, 等. 粉末冶金CNTs/Cu复合材料的显微组织与力学性能[J]. 粉末冶金材料科学与工程, 2016, 21(1): 129-136. PENG Gang, CAI Xiaolan, ZHOU Lei, et al.Microstructure and mechanical properties of CNTs/Cu composites fabricated by powder metallurgy[J]. Materials Science and Engineering of Powder Metallurgy, 2016, 21(1): 129-136. [15] SHUKLA A K, NARAYANA MURTY S V S, SHARMA S C, et al. The serrated flow and recrystallization in dispersion hardened Cu-Cr-Nb alloy during hot deformation[J]. Materials Science and Engineering A, 2016, 673: 135-140. [16] ELLIS D L, CARTER J L W, FERRY M H. A statistical study of the effects of processing upon the creep properties of GRCop-84[J]. Materials Science and Engineering A, 2015, 640: 1-15. [17] DHOKEY N B, SARVE S N, LAMSOGE H A.Development of in-situ synthesis of Cr2Nb reinforced copper alloy by aluminothermic process[J]. Transactions of the Indian Institute of Metals, 2011, 64(4/5): 425-429. [18] DHOKEY N B, SARVE S N, LAMSOGE H A.In-situ Synthesis of Cr2Nb reinforced copper alloy by liquid metallurgy route[J]. Materials Science Forum, 2012, 710: 143-148. [19] SHUKLA A K, NARAYANA MURTY S V S, SURESH KUMAR R, et al. Effect of powder milling on mechanical properties of hot-pressed and hot-rolled Cu-Cr-Nb alloy[J]. Journal of Alloys and Compounds, 2013, 580: 427-434. [20] SHUKLA A K, NARAYANA MURTY S V S, SURESH KUMAR R, et al. Densification behavior and mechanical properties of Cu-Cr-Nb alloy powders[J]. Materials Science and Engineering A, 2012, 551: 241-248. [21] SHUKLA A K, SAMUEL M G, SURESH KUMAR R, et al.Effect of powder oxidation on densification and properties of vacuum hot pressed Cu-Cr-Nb alloy[J]. Materials Science and Engineering A, 2013, 561: 452-459. [22] LÜ X Q, LIU Z M, LEI T, et al.Effect of heat treatment on Cr2Nb phase and properties of spark plasma sintered Cu-2Cr-1Nb alloy[J]. Materials, 2020, 13(12): 2860. [23] 田杰, 黄正华, 戚文军, 等. 金属选区激光熔化的研究现状[J]. 材料导报, 2017, 31(29): 90-101. TIAN Jie, HUANG Zhenghua, QI Wenjun, et al.Research progress on selective laser melting of metal[J]. Materials Reports, 2017, 31(29): 90-101. [24] ZHANG S, ZHU H, ZHANG L, et al.Microstructure and properties of high strength and high conductivity Cu-Cr alloy components fabricated by high power selective laser melting[J]. Materials Letters, 2018, 237: 306-309. [25] SCUDINO S, UNTERDöRFER C, PRASHANTH K G, et al. Additive manufacturing of Cu-10Sn bronze[J]. Materials Letters, 2015, 156: 202-204. [26] JADHAV S D, DHEKNE P P, BRODU E, et al.Laser powder bed fusion additive manufacturing of highly conductive parts made of optically absorptive carburized CuCr1 powder[J]. Materials & Design, 2021, 198: 109369. [27] IKESHOJI T-T, NAKAMURA K, YONEHARA M, et al.Selective laser melting of pure copper[J]. Journal of Metals, 2018, 70(3): 396-400. [28] UCHIDA S, KIMURA T, NAKAMOTO T, et al.Microstructures and electrical and mechanical properties of Cu-Cr alloys fabricated by selective laser melting[J]. Materials & Design, 2019, 175: 107815. [29] MA Z, ZHANG K, REN Z, et al.Selective laser melting of Cu-Cr-Zr copper alloy: parameter optimization, microstructure and mechanical properties[J]. Journal of Alloys and Compounds, 2020, 828: 154350. [30] DINDA G P, DASGUPTA A K, MAZUMDER J.Texture control during laser deposition of nickel-based superalloy[J]. Scripta Materialia, 2012, 67(5): 503-506. [31] BAHL S, MISHRA S, YAZAR K U, et al.Non-equilibrium microstructure, crystallographic texture and morphological texture synergistically result in unusual mechanical properties of 3D printed 316L stainless steel[J]. Additive Manufacturing, 2019, 28: 65-77. |
|
|
|