快速制备C<sub>f</sub>/SiC复合材料的组织与力学性能

doi:10.19976/j.cnki.43-1448/TF.2021083

Abstract
Figure/Table
References
Related Citation (10)

Download: PDF (1124 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract C_f/SiC ceramic matrix composites were prepared byslurry brushing-needle punching-warm pressure curing- high temperature carbonization proces using SiC powders, alcohol-soluble phenolic resin powders, carbon fiber felt and carbon fibers weft free cloth as raw materials. The C_f/SiC porous preform was prepared by slurry brush coating, puncture, temperature pressure curing and high temperature carbonization. The volume fraction of phenolic resin in the slurry was respectively 10% and 15%, and temperature and pressure curing pressures was 8 MPa and 20 MPa, respectively. And then SiC was deposited by chemical vapor infiltration method to quickly prepare C_f/SiC ceramic matrix composites. The morphology and microstructure of the materials were observed and analyzed. The properties such as density, porosity, bending strength and fracture toughness of the materials were measured. The results show that the properties of C_f/SiC composites are better when the volume fraction of phenolic resin in the slurry is low, and the properties increase with the increase of curing pressure. When the volume fraction of phenolic resin was 10% and the curing pressure was 20 MPa, a high density C_f/SiC composite with open porosity of 13.1% is obtained. The matrix of C_f/SiC composite was relatively compact, and there was almost no pores between the fiber bundles and the matrix. When the composite was subjected to the applied load, the strength and toughness of the composite were improved by fiber pulling out, fiber debonding and crack deflection. The fracture mode of the composite was pseudoplastic fracture, with the highest bending strength and fracture toughness of 570 MPa and 18.6 MPa·m^1/2, respectively.

Key words： C_f/SiC composites slurry needling chemical vapor infiltration bending strength fracture toughness

Received: 16 September 2021 Published: 28 February 2022

ZTFLH:

TB332

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	WANG Yang
	LI Guodong
	YU Shijie
	JIANG Yi

Cite this article:

WANG Yang,LI Guodong,YU Shijie, et al. Microstructure and mechanical properties of rapid prepared C_f/SiC composites[J]. Materials Science and Engineering of Powder Metallurgy, 2022, 27(1): 92-101.

URL:

http://pmbjb.csu.edu.cn/EN/10.19976/j.cnki.43-1448/TF.2021083 OR http://pmbjb.csu.edu.cn/EN/Y2022/V27/I1/92

[1] DUAN J J, ZHANG M H, CHEN P J, et al.Tribological behavior and applications of carbon fiber reinforced ceramic composites as high-performance frictional materials[J]. Ceramics International, 2021, 47(14): 19271-19281.
[2] NIU X M, SUN Z G, SONG Y D.Transverse tensile properties of 3 dimension-4 directional braided C_f/SiC composite based on double-scale model[J]. Applied Composite Materials, 2018, 25(5): 1001-1019.
[3] YOON B, KIM M, KIM J, et al.Study on improvement of mechanical property, oxidation and erosion resistance of SiC matrix ceramic composites reinforced by hybrid fabric composed of SiC and carbon fiber[J]. Composites Research, 2019, 32(3): 148-157.
[4] ZHANG K, ZHANG L, HE R, et al.Joining of C_f/SiC ceramic matrix composites: A review[J]. Advances in Materials Science and Engineering, 2018, 2018( 3): 15-30.
[5] 陈明伟, 谢巍杰, 邱海鹏. 连续碳化硅纤维增强碳化硅陶瓷基复合材料研究进展[J]. 现代技术陶瓷, 2016, 37(6): 393-402.
CHEN Mingwei, XIE Weijie, QIU Haipeng.Recent progress in continuous SiC fiber reinforced SiC ceramic matrix composites[J]. Advanced Ceramics, 2016, 37(6): 393-402.
[6] 左平, 何爱杰, 李万福, 等. 连续纤维增韧陶瓷基复合材料的发展及在航空发动机上的应用[J]. 燃气涡轮试验与研究, 2019, 32(5): 47-52.
ZUO Ping, HE Aijie, LI Wanfu, et al.Application of continuous fiber reinforced ceramic matrix composites on aero-engine[J]. Gas Turbine Experiment and Research, 2019, 32(5): 47-52.
[7] WEI J H, LIN B, WANG H J, et al.Friction and wear characteristics of carbon fiber reinforced silicon carbide ceramic matrix (C_f/SiC) composite and zirconia (ZrO₂) ceramic under dry condition[J]. Tribology International, 2018, 119: 45-54.
[8] FAN X M, YIN X W.Progress in research and development on matrix modification of continuous fiber-reinforced silicon carbide matrix composites[J]. Advanced Composites and Hybrid Materials, 2018, 1(4): 685-695.
[9] KRISHNARAO R V, REDDY G M.Joining of C_f/SiC composites and ZrB₂-SiC based composites for ultra high temperature applications[J]. Ceramics International, 2018, 44(9): 10569-10578.
[10] 陈智勇, 刘建寿, 徐颖强, 等. 碳纤维增韧碳化硅陶瓷基复合材料界面相的研究进展[J]. 陶瓷学报, 2019, 40(6): 701-709.
CHEN Zhiyong, LIU Jianshou, XU Yingqiang, et al.Research progress on the interphase of C/SiC composites[J]. Journal of Ceramics, 2019, 40(6): 701-709.
[11] KILTEMEYER M, SCHOMER L, HELMREICH T, et al.Fabrication of ultra high temperature ceramic matrix composites using a reactive melt infiltration process[J]. Journal of the European Ceramic Society, 2016, 36(15): 3647-3655.
[12] ZHANG J M, CHEN X W, LIAO C J, et al.Optimizing microstructure and properties of SiC_f/SiC composites prepared by reactive melt infiltration[J]. Journal of Inorganic Materials, 2021, 36(10): 1103-1110.
[13] CHEN X W, FENG Q, GAO L, et al.Interphase degradation of three-dimensional C_f/SiC-ZrC-ZrB₂ composites fabricated via reactive melt infiltration[J]. Journal of the American Ceramic Society, 2017, 100(10): 4816-4826.
[14] HE F, LIU Y S, TIAN Z, et al.Improvement of the strength and toughness of carbon fiber/SiC composites via chemical vapor infiltration-grown SiC nanowire interphases[J]. Ceramics International, 2018, 44(2): 2311-2319.
[15] LIANG J J, XIAO H N, GAO P Z, et al.Microstructure and properties of 2D-C_f/SiC composite fabricated by combination of CVI and PIP process with SiC particle as inert fillers[J]. Ceramics International, 2017, 43(2): 1788-1794.
[16] SINGH S, YIN J, FENG L, et al.Significance of modification of slurry infiltration process for the precursor impregnation and pyrolysis process of SiC_f/SiC composites[J]. Journal of the European Ceramic Society, 2020, 40(54): 2245-2251.
[17] 孙晔华, 李国栋, 叶国柱, 等. 炭纤维涂层改性对快速制备C_f/SiC复合材料力学性能的影响[J]. 粉末冶金材料科学与工程, 2019, 24(3): 248-254.
SUN Yehua, LI Guodong, YE Guozhu, et al.Effect of carbon fiber coating modification on mechanical properties of rapidly prepared C/SiC composite[J]. Materials Science and Engineering of Powder Metallurgy, 2019, 24(3): 248-254.
[18] 孟祥玮, 吴西士, 裴兵兵, 等. 短碳纤维增强碳化硅基复合材料的制备与力学性能[J]. 无机材料学报, 2019, 34(9): 1015-1020.
MENG Xiangwei, WU Xishi, PEI Bingbing, et al.Preparation and mechanical property of short carbon fiber reinforced silicon carbide matrix composites[J]. Journal of Inorganic Materials, 2019, 34(9): 1015-1020.
[19] CHANG Y H, HSU H Y, YEH J H, et al.Synthesis and characterization of carbon fiber-reinforced silicon carbide composites with an interlayer of amorphous carbon thin film prepared by precursor infiltration and pyrolysis processes[J]. Advanced Engineering Materials, 2019, 21(2): 1800583.
[20] KIM K M, HAHN Y, LEE S M, et al.Mechanical properties of C_f/SiC composite using a combined process of chemical vapor infiltration and precursor infiltration pyrolysis[J]. Journal of the Korean Ceramic Society, 2018, 55(4): 392-399.