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Effects of ZrN doping on magnetic properties and electrical resistivity of NdFeB magnets prepared by hot pressing and hot deformation |
BAI Yang1,2, WANG Ziliang2, LI Yajing1,2, ZUO Siyuan2, FANG Yikun3, ZHU Minggang3, HUANG Guangwei2, ZHENG Liyun1,2 |
1. School of Mechanical and Equipment Engineering, Hebei University of Engineering, Handan 056038, China; 2. Hebei Engineering Research Centre for Rare Earth Permanent Magnetic Materials & Applications, Hebei University of Engineering, Handan 056038, China; 3. Functional Materials Division, Central Iron & Steel Research Institute, Beijing 100081, China |
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Abstract NdFeB magnets with different mass fractions of ZrN were prepared by mixing ZrN and NdFeB melt quenching powder evenly, followed by hot pressing and hot deformation. The effects of ZrN doping on the hot pressing density, magnetic properties, uniformity and electrical resistivity of the hot pressed and hot deformed NdFeB magnets were studied. The results show that the magnetic properties in the interior of the hot pressed magnet are the best, which gradually deteriorate along the radial direction. With the increase of the mass fraction of ZrN, the density of the hot pressed magnets increases first and then decreases. The electrical resistivity of the hot deformed magnets gradually increases with the mass fraction of ZrN, while the magnetic properties decrease linearly. When the mass fraction of ZrN is 1%, the remanence magnetization, the coercivity, the maximum magnetic energy product are 1.362 T, 865.5 kA/m and 349.6 kJ/m3, respectively. And the resistivity is 250 μΩ∙cm. Compared with that of the undoped hot deformed NdFeB magnet (230 μΩ∙cm), the resistivity of the doped NdFeB magnet increases by about 8.7%.
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Received: 20 January 2021
Published: 21 July 2021
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Cite this article: |
BAI Yang,WANG Ziliang,LI Yajing, et al. Effects of ZrN doping on magnetic properties and electrical resistivity of NdFeB magnets prepared by hot pressing and hot deformation[J]. Materials Science and Engineering of Powder Metallurgy, 2021, 26(3): 257-262.
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URL: |
http://pmbjb.csu.edu.cn/EN/ OR http://pmbjb.csu.edu.cn/EN/Y2021/V26/I3/257 |
[1] 严静妮, 窦满峰, 吴转峰. 稀土永磁同步电动机转子温升探讨[J]. 微电机, 2006, 39(8): 38-39. YAN Jingni, DOU Manfeng, WU Zhuanfeng.Discussion on rotor temperature rise of rare earth permanent magnet synchronous motor[J]. Micromotors, 2006, 39(8): 38-39. [2] 刘荣明. 中国稀土永磁产业现状及技术发展新动向[J]. 新材料产业, 2013(1): 25-32. LIU Rongming.Current situations and new trends in technological development of rare earth permanent magnet industry in China[J]. Advanced Materrials Industry, 2013(1): 25-32. [3] 稀土永磁电机大规模产业化条件已具备[J]. 中国粉体工业, 2011(4): 53-53. The conditions for large-scale industrialization of rare earth permanent magnet motors are ready[J]. China Powder Industry, 2011(4): 53-53. [4] 谢述锋, 王岳, 王德义. 一种高磁性能高电阻率稀土永磁体及其制备方法: 200910227793[P].2010-06-16. XIE Shufeng, WANG Yue, WANG Deyi. A kind of rare earth permanent magnet with high magnetic property and high resistivity and its preparation method: 200910227793[P].2010-06-16. [5] 王晓军, 李文学, 严俊萍, 等. 热变形钕铁硼永磁材料组织结构的研究[J]. 包头钢铁学院院报, 2003, 22(4): 327-330. WANG Xiaojun, LI Wenxue, YAN Junping, et al.Study on microstructure of thermally deformed NdFeB permanent magnet material[J]. Journal of Baotou Iron and Steel Institute, 2003, 22(4): 327-330. [6] 郑立允, 叶利平, 毕文超, 等. 纳米Al2O3掺杂对 NdFeB磁体磁性能和电阻率的影响[J]. 磁性材料及器件, 2013, 44(3): 27-30. ZHENG Liyun, YE Liping, BI Wenchao, et al.Effect of nano- Al2O3 doping on magnetic properties and resistivity of NdFeB magnets[J]. Magnetic Materials and Devices, 2013, 44(3): 27-30. [7] 白帆, 郑立允, 朱明刚, 等. 热压/热变形(Nd,Ce)2Fe14B/CaF2磁体的磁电性能和微结构[J]. 磁性材料及器件, 2016, 47(3): 4-7. BAI Fan, ZHENG Liyun, ZHU Minggang, et al.Electromagnetic properties and microstructures of hot-pressed/hot-deformed (Nd,Ce)2Fe14B/CaF2 magnets[J]. Magnetic Materials and Devices, 2016, 47(3): 4-7. [8] WU W, DUNLOP J B, COLLOCOTT S J.Modelling of eddy- current losses in a surface-mounted NdFeB permanent-magnet generator[C]// Proceedings of Seventeenth International Workshop on Rare-earth Magnets and Applications. Newark, Delaware, USA, 2002: 328-328. [9] 徐芳, 董显平, 张澜庭, 等. 添加MgF2对烧结NdFeB磁体的性能和微观组织的影响[J]. 中国稀土学报, 2011, 29(5): 523-527. XU Fang, DONG Xianping, ZHANG Lanting, et al.Effect of MgF2 on the properties and microstructure of sintered NdFeB magnets[J]. Chinese Journal of Rare Earth Sciences, 2011, 29(5): 523-527. [10] 王红玉, 潘建峰, 王艳, 等. 热变形(Nd,Pr)-Fe-Nb-B磁体取向度及矫顽力机制研究[J]. 稀有金属, 2017, 41(6): 641-647. WANG Hongyu, PAN Jianfeng, WANG Yan, et al.Study on the direction and coercive force of thermal deformed (Nd,Pr)-Fe- Nb-B Magnet[J]. Rare Metals, 2017, 41(6): 641-647. [11] LEONOWIEZ M, DAVIES H A.Effect of Nd content on induced anisotropy in hot deformed Fe-N-B magnets[J]. Materials Letters, 1994, 19(5/6): 275-279. [12] TANG X, CHEN R, YIN W Z et al. Mechanism analysis of coercivity enhancement of hot deformed Nd-Fe-B magnets by DyF3 diffusion[J]. IEEE Transactions on Magnetics, 2013, 49(7): 3237-3239. [13] WATANABE N, ITAKURA M, NISHIDA M. Microstructure of high coercivity Nd-Fe- Co-Ga-B hot-deformed magnet improved by the Dy diffusion treatment[J]. Journal of Alloys and Compounds, 2013, 557, 25: 1-4. [14] SAWATZKI S, DIRBA I, WENDROCK H, et al. Diffusion processes in hot-deformed Nd-Fe-Bmagnets with DyF3, additions[J]. Journal of Magnetism and Magnetic Materials, 2014, 358/359(5): 163-169. [15] SAWATZKI S, DIRKS A, FRINCU B, et al. Coercivity enhancement in hot-pressed Nd-Fe-B permanent magnets with low melting eutectics[J]. Journal of Applied Physics, 2014, 115(17): 17A705. |
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