|
|
Effect of B4C particles on microstructure and mechanical properties of C/C-SiC composites |
TANG Zhenxiao, PENG Ke, XIANG Qiuling, YI Jun, YI Maozhong |
State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083 |
|
|
Abstract B4C particles modified C/C-SiC composites were prepared by slurry infiltration combined with precursor infiltration and pyrolysis. The effect of the addition of B4C particles on the mechanical properties of C/C-SiC composites was investigated. The results show that,the flexural strength and fracture toughness of B4C particles modified C/C-SiC composites are 250.41 MPa and 13.56 MPa·m1/2, respectively. Compared with C/C-SiC composites, the flexural strength decreases by 45.5%, the toughness increases by 46.0%. The B4C particles can promote the sintering of SiC matrix. However, the bending strength of the composites decrease due to the formation of a large number of closed pores and weak interfaces of the matrix. The main reason for the improvement of the fracture toughness of the C/C-SiC composites modified by B4C particles is that the weak interface between B4C particles and SiC matrix make the cracks deflect effectively in the SiC matrix, increase the propagation path of the cracks in the matrix, and improve the fracture toughness of the composites.
|
Received: 04 September 2019
Published: 19 June 2020
|
|
|
|
|
[1] NASLAIN R, GUETTE A, REBILLAT F, et al.Oxidation mechanisms and kinetics of SiC-matrix composites and their constituents[J]. Journal of Materials Science, 2004, 39(24): 7303-7316. [2] KRENKEL W, BERNDT F.C/C-SiC composites for space applications and advanced friction systems[J]. Materials Science & Engineering A, 2005, 412(1/2): 177-181. [3] YAN Zhiqiao, XIONG Xiang, XIAO Peng, et al.Oxidation behavior of oxidation protective coatings for C/C-SiC composites at 1 500 ℃[J]. Transactions of Nonferrous Metals Society of China, 2009, 19(1): 61-64. [4] DAMJANOVIC T, ARGIRUSIS Chr, JOKANOVIC B, et al.Oxidation protection of C/C-SiC composites by an electrophoretically deposited mullite precursor: Cyclic thermo gravimetric analysis[J]. Journal of the European Ceramic Society, 2006, 27(2): 150-169. [5] 代吉祥, 沙建军, 王永昌, 等. C/C-SiC-ZrC复合材料的制备及其力学性能[J]. 稀有金属材料与工程, 2016, 45(3): 742-748. DAI Jixiang, SHA Jianjun, WANG Yongchang, et al.Preparation and mechanical properties of C/C-SiC-ZrC composites[J]. Rare Metal Materials and Engineering, 2016, 45(3): 742-748. [6] 石小磊. 第二相对复相结构陶瓷力学性能的影响研究[D]. 大连: 大连理工大学, 2010. SHI Xiaolei.Study on influence of second phase on mechanical properties of composite structure ceramics[D]. Dalian University of Technology, 2010. [7] 童长青, 成来飞, 殷小玮, 等. 浆料浸渍结合反应熔渗法制备2D C/SiC-ZrB2复合材料[J]. 航空材料学报, 2009, 29(4): 77-80. TONG Changqing, CHENG Laifei, YIN Xiaowei, et al.Processin of 2D C/SiC-ZrB2 composites by slurry infiltration and reactive melt infiltration[J]. Journal of Aeranautical Materials, 2009, 29(4): 77-80. [8] 冉丽萍, 刘亦奇, 杨琳, 等. 基体炭对反应熔渗法制备的C/C-SiC复合材料性能的影响[J]. 粉末冶金材料科学与工程, 2011, 16(3): 374-378. RAN Liping, LIU Yiqi, YANG Lin, et al.Effect of matrix carbon on properties of C/C-SiC composites fabricated by RMI[J]. Materials Science and Engineering of Powder Metallurgy, 2011, 16(3): 374-378. [9] 曹柳絮. PIP及RMI法制备C/C-SiC复合材料过程及其性能研究[D]. 长沙: 中南大学, 2014. CAO Liuxu.Preparation and properties of C/C-SiC composites prepared by PIP and RMI[D]. Changsha: Central South University, 2014. [10] 巫红燕. B4C/SiC陶瓷基复合材料的反应熔渗制备及其结构与性能研究[D]. 杭州: 浙江大学, 2013. WU Hongyan.Fabrication of B4C/SiC ceramic matrix composites by reactive melt infiltration and their structure and mechanical properties[D]. Hangzhou:Zhejiang University, 2013. [11] 刘泽潭. B4C-TiB2复相陶瓷的制备及性能研究[D]. 合肥: 安徽工业大学, 2018. LIU Zetan.Preparation and properties of composites B4C-TiB2 ceramics[D]. Hefei: Anhui University of Technology, 2018. [12] 冯毅. 原位法制备B4C-CNTs复合陶瓷及其增韧机理研究[D]. 西安: 西安理工大学, 2017. FENG Yi.In-situ fabrication of B4C-CNTs composite ceramics and their toughening mechanism[D]. Xi’an: Xi’an University of Technology, 2017. [13] 马彦. PIP法Cf/SiC复合材料组成、结构及性能高温演变研究[D]. 长沙: 国防科学技术大学, 2011. MA Yan.High-temperature evolutions of the compositions, microstructures and properties of C/SiC composites fabricated via the PIP route[D]. Changsha: National University of Defense Technology, 2011. [14] 赵菁. SiC多孔陶瓷材料制备、组织与性能的研究[D]. 长春:东北大学, 2016. ZHAO Jing.Preparation, microstructure and properties of porous SiC ceramics[D]. Changchun: Northeastern University, 2016. [15] FAN S, HE L, YANG C, et al.Effect of B4C on the microstructure and properties of B4C modified three-dimensional needled C/C-SiC composites[J]. Materials Science and Engineering A, 2017, 706: 201-210. [16] FAN Qianguo, CUI Hong, YAN Liansheng, et al.Ablation resistance properties of ultra-high temperature composites C/C-SiC-ZrB2 by Slurry Impregnation Method[J]. Journal of Inorganic Materials, 2013, 28(9): 1014-1018. [17] 尹欢, 彭可, 饶菲, 等. 高固相含量浆料浸渗法制备C/C-SiC复合材料及其性能[J]. 粉末冶金材料科学与工程, 2018, 23(5): 539-546. YIN Huan, PENG Ke, RAO Fei, et al.Preparation and properties of C/C-SiC composites by high-solid-loading slurry impregnation[J]. Materials Science and Engineering of Powder Metallurgy, 2018, 23(5): 539-546. [18] CHO Junyoung, AN Taeho, JI Sanggu, et al.The effects of B4C addition on the microstructure and mechanical properties of SiC prepared using powders recovered from kerf loss sludge[J]. Ceramics International, 2017, 43(17): 15332-15338. [19] LIU Yongsheng, CHENG Laifei, ZHANG Litong, et al.Fracture behavior and mechanism of 2D C/SiC-BCx composite at room temperature[J]. Materials Science and Engineering A, 2011, 528(3). |
|
|
|