Nd3+、Sm3+和Eu3+单掺杂NiTiO3的光电磁性能

doi:10.19976/j.cnki.43-1448/TF.2023066

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Abstract Nanosized Ni_1-_xR_xTiO₃ (R=Nd, Sm and Eu; x=0, 0.05 and 0.1) powders were synthesized by sol-gel method. The effects of Nd, Sm, and Eu doping on the microstructure and optical, electrical, and magnetic properties of NiTiO₃ were systematically studied using characterization techniques such as X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, and physical property measurement system. The results show that all samples exhibit charge transfer of O—Ti bonds and O—Ni bonds (200-365 nm), spin-allowed transition of Ni²⁺ from ³A_2g(³F) to ³T_1g(³P) (450 nm), spin-forbidden transitions of ¹T_2g(¹D) and ¹A_1g(¹G) (490-520 nm), and spin-forbidden transition of ¹E_g(¹D) (743 nm). Absorption spectra of Nd- doped samples exhibit an absorption peak near 588 nm correlated with the electronic transition of Nb³⁺ at the octahedral position, which change the samples color from yellow to green. All samples exhibit antiferromagnetism and ferroelectricity at room temperature, and Nd, Sm, and Eu doping at the Ni site significantly enhance the ferroelectricity of NiTiO₃. Doping elements with larger ionic radii cause lattice distortion, promote the rotation of ferroelectric domains, and enhancc the ferroelectricity.

Key words： NiTiO₃ ferromagnetism ferroelectricity doping sol-gel method

Received: 25 July 2023 Published: 23 January 2024

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	YU Pengfei
	TURSUN Rabigul

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YU Pengfei,TURSUN Rabigul. Optical, electrical, and magnetic properties of Nd³⁺, Sm³⁺, and Eu³⁺ single-doped NiTiO₃[J]. Materials Science and Engineering of Powder Metallurgy, 2023, 28(6): 522-533.

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http://pmbjb.csu.edu.cn/EN/10.19976/j.cnki.43-1448/TF.2023066 OR http://pmbjb.csu.edu.cn/EN/Y2023/V28/I6/522

[1] LEUNG C M, LI J, VIEHLAND D, et al.A review on applications of magnetoelectric composites: from heterostructural uncooled magnetic sensors, energy harvesters to highly efficient power converters[J]. Journal of Physics D-Applied Physics, 2018, 51: 263002.
[2] SUN H Y, WANG J R, WANG Y S, et al.Nonvolatile ferroelectric domain wall memory integrated on silicon[J]. Nature Communications, 2022, 13(1): 4332.
[3] ZHANG X Y, WANG Y, GAO X Y, et al.High-temperature and flexible piezoelectric sensors for lamb-wave-based structural health monitoring[J]. ACS Applied Materials & Interfaces, 2021, 13(40): 47764-47772.
[4] ASTAFEV P, PAVELKO A, LERER A, et al.Microwave- absorbing properties of PbMg_1/3Nb_2/3O₃-PbZrO₃-PbTiO₃- PbGeO₃ (PMN-PZT-PG) solid solutions on a microstrip line in the microwave range[J]. Crystals, 2022, 12(4): 551.
[5] XIN C, WANG Y, SUI Y, et al.Electronic, magnetic and multiferroic properties of magnetoelectric NiTiO₃[J]. Journal of Alloys and Compounds, 2014, 613: 401-406.
[6] RUIZ-PRECIADO M A, BULOU A, MAKOWSKA- JANUSIK M, et al. Nickel titanate (NiTiO₃) thin films: RF-sputtering synthesis and investigation of related features for photocatalysis[J]. Crystengcomm, 2016, 18(18): 3229-3236.
[7] YAMAMOTO O, TAKEDA Y, KANNO R, et al.Perovskite-type oxides as oxygen electrodes for high temperature oxide fuel cells[J]. Solid State Ionics, 1987, 22: 241-246.
[8] SOBHANI-NASAB A, HOSSEINPOUR-MASHKAIN S M, SALAVATI-NIASARI M, et al. Synthesis, characterization, and photovoltaic application of NiTiO₃ nanostructures via two-step sol-gel method[J]. Journal of Materials Science- Materials in Electronics, 2015, 26(8): 5735-5742.
[9] SUBRAMANIAN S, GANAPATHY S, DHARMALINGAM S, et al.Enhanced charge carrier transfer process in nickel titanate nanostructures for environmental remediation of industrial dye[J]. Environmental Science and Pollution Research, 2023, 30(27): 70011-70021.
[10] MAAFA I M, ALI M A.Enhanced organic pollutant removal efficiency of electrospun NiTiO₃/TiO₂-decorated carbon nanofibers[J]. Polymers, 2023, 15(1): 109.
[11] CHUNG K H, LAM S S, PARK Y K, et al.Preparation of nickel-bismuth titanates enhanced visible-light photosensitivity and their photocatalytic properties for hydrogen generation by plasma cracking[J]. Molecular Catalysis, 2023, 545: 113239.
[12] PISHCH I V, RADION E V.Production of pigments with a perovskite-like structure based on nickel titante by the precitation method[J]. Glass and Ceramics, 2003, 60(5/6): 154-157.
[13] ASLAN E, TOY E, GUNER Z, et al.The effect of various nickel oxide ratios on the color and reflectivity of PY53 nickel-titanate yellow pigment[J]. Results in Chemistry, 2022, 4: 100662.
[14] KASHANI F Z, GHOREISHI S M, KHOOBI A, et al.A carbon paste electrode modified with a nickel titanate nanoceramic for simultaneous voltammetric determination of ortho- and para-hydroxybenzoic acids[J]. Microchimica Acta, 2018, 186(1): 12.
[15] OBAYASHI H, SAKURAI Y, GEJO T.Perovskite-type oxides as ethanol sensors[J]. Journal of Solid State Chemistry, 1976, 17(3): 299-303.
[16] VARGA T, DROUBAY T C, BOWDEN M E, et al.Epitaxial growth of NiTiO₃ with a distorted ilmenite structure[J]. Thin Solid Films, 2012, 520(17): 5534-5541.
[17] TURSUN R B, SU Y C, YU Q S, et al.Room-temperature coexistence of electric and magnetic orders in NiTiO₃ and effect of ethylene glycol[J]. Materials Science and Engineering B, 2018, 228: 96-102.
[18] YUVARAJ S, NITHYA V D, FATHIMA K S, et al.Investigations on the temperature dependent electrical and magnetic properties of NiTiO₃ by molten salt synthesis[J]. Materials Research Bulletin, 2013, 48(3): 1110-1116.
[19] HACHIMI A G, ZAARI H, HAMEDOUN M, et al.Experimental and theoretical investigation of Nd doped ZnO[J]. Journal of Magnetism and Magnetic Materials, 2017, 444: 416-420.
[20] KUMARI A, KUMARI K, AHMED F, et al.Influence of Sm doping on structural, ferroelectric, electrical, optical and magnetic properties of BaTiO₃[J]. Vacuum, 2021, 184: 109872.
[21] ZAFAR A, RAHMAN A, SHAHZADA S, et al.Electrical and magnetic properties of nano-sized Eu doped barium hexaferrites[J]. Journal of Alloys and Compounds, 2017, 727(15): 683-690.
[22] TONG Y P, CHEN Z, WANG H X, et al.Fabrication and characterization of environmental-friendly Ni₁-_xR_xTiO₃ nanopigments with high NIR reflectance[J]. Functional Materials Letters, 2015, 8(5): 1550050.
[23] SADJADI M S, ZARE K, KHANAHMADZADEH S, et al.Structural characterization of NiTiO₃ nanopowders prepared by stearic acid gel method[J]. Materials Letters, 2008, 62(21/22): 3679-3681.
[24] RUIZ-PRECIADO M A, KASSIBA A, GIBAUD A, et al. Comparison of nickel titanate (NiTiO₃) powders synthesized by sol-gel and solid state reaction[J]. Materials Science in Semiconductor Processing, 2015, 37: 171-178.
[25] GUIET A, HUAN T N, PAYEN C, et al.Copper-substituted NiTiO₃ ilmenite-type materials for oxygen evolution reaction[J]. ACS Applied Materials & Interfaces, 2019, 11(34): 31038-31048.
[26] NITHYA V D, SELVAN R K, KARTHIKEYAN K, et al.Impact of Si⁴+ ions doping on the electrochemical cycling performance of NiTiO₃ as anodes for Li-ion batteries[J]. Journal of Nanoscience and Nanotechnology, 2015, 15(1): 694-702.
[27] IMANI M, RADMANESH L, TADJARODI A.Synthesis and study of the pseudocapacitive behavior of heterojunctional NiTiO₃-based chitosan nanocomposite[J]. Journal of Physics and Chemistry of Solids, 2020, 139: 109309.
[28] HUANG Z D, ZHANG T T, LU H, et al.Grain- boundary- rich mesoporous NiTiO₃ micro-prism as high tap-density, super rate and long life anode for sodium and lithium ion batteries[J]. Energy Storage Materials, 2018, 13: 329-339.
[29] NUNE S V K. NiTiO₃ nanocomposite: solvo-thermal synthesis and its application in environmental remediation[J]. Materials Today: Proceedings, 2019, 19: 2697-2701.
[30] INCEESUNGVORN B, TEERANUNPONG T, NUNKAEW J, et al.Novel NiTiO₃/Ag₃VO₄ composite with enhanced photocatalytic performance under visible light[J]. Catalysis Communications, 2014, 54: 35-38.
[31] SIDDAIAH T, GOPAL N O.Doping Na+ into polyvinyl alcohol: nethacrylic acid-ethyl acrylate (PVA/MAA:EA) polymer blend electrolytes; a way to improve the blend’s thermal, structural, optical and electrical properties[J]. Journal of Macromolecular Science. Physics, 2023, 61(10/11): 1451-1462.
[32] LIU X, HONG R, TIAN C.Tolerance factor and the stability discussion of ABO₃-type ilmenite[J]. Journal of Materials Science-Materials in Electronics, 2008, 20(4): 323-327.
[33] ZHAO Z T, GUO R F, MAO H R, et al.Effect of components on the microstructures and properties of rare-earth zirconate ceramics prepared by ultrafast high-throughput sintering[J]. Journal of the European Ceramic Society, 2021, 41(11): 5768-5773.
[34] INCEESUNGVORN B, TEERANUNPONG T, NUNKAEW J, et al.Novel NiTiO₃/Ag₃VO₄ composite with enhanced photocatalytic performance under visible light[J]. Catalysis Communications, 2014, 54: 35-38.
[35] YANG G R, CHANG W, YAN W.Fabrication and characterization of NiTiO₃ nanofibers by sol-gel assisted electrospinning[J]. Journal of Sol-Gel Science and Technology, 2014, 69(3): 473-479.
[36] SAKAMOTO K, HAYASHI F, SATO K, et al.XPS spectral analysis for a multiple oxide comprising NiO₂, TiO₂, and NiTiO₃[J]. Applied Surface Science, 2020, 526: 146729.
[37] MOMOSE Y, TSURUYA K, SAKURAI T, et al.Photoelectron emission and XPS studies of real iron surfaces subjected to scratching in air, water, and organic liquids[J]. Surface and Interface Analysis, 2016, 48(4): 202-211.
[38] TZENG B C, SELVAM T, TSAI M H.M(II)- dipyridylamide-based coordination frameworks (M=Mn, Co, Ni): structural transformation[J]. Journal of Solid State Chemistry, 2016, 243: 70-76.
[39] CUMMINS T R, EGDELL R G.Electron energy in Nd₂-_xCe_xCuO₄: a study by valence and core-level photoemission spectroscopy[J]. Physical Review B, 1993, 48(9): 6556-6568.
[40] KOMPA A, MURARI M S, KEKUDA D, et al.Low concentration rare earth doping (Nd) and its effect on structural properties of titania thin films[J]. Ceramics International, 2021, 47(10): 13480-13487.
[41] WEI L G, YANG Y L, XIA X, et al.Band edge movement in dye sensitized Sm-doped TiO₂ solar cells: a study by variable temperature spectroelectrochemistry[J]. RSC Advances, 2015, 5(86): 70512-70521.
[42] MERCIER F, ALLIOT C, BION L, et al.XPS study of Eu (III) coordination compounds: core levels binding energies in solid mixed-oxo-compounds Eu_mX_xO_y[J]. Journal of Electron Spectroscopy and Related Phenomena, 2006, 150(1): 21-26.
[43] BELLAM J B, RUIZ-PRECIADO M A, EDELY M, et al. Visible-light photocatalytic activity of nitrogen-doped NiTiO₃ thin films prepared by a co-sputtering process[J]. RSC Advances, 2015, 5(14): 10551-10559.
[44] LOPES K P, CAVALCANTE L S, SIMOES A Z, et al.NiTiO₃ powders obtained by polymeric precursor method: synthesis and characterization[J]. Journal of Alloys and Compounds, 2009, 468(1/2): 327-332.
[45] KARMAKAR S, MANNA A K, VARMA S, et al.Investigation of optical, electrical and magnetic properties of hexagonal NiTiO₃ nanoparticles prepared via ultrasonic dispersion techniques for high power applications[J]. Materials Research Express, 2018, 5(5): 055037.
[46] BARATON M I, BUSCA G, PRIETO M C, et al.On the vibrational spectra and structure of FeCrO₃ and of the ilmenite-type compounds CoTiO₃ and NiTiO₃[J]. Journal of Solid State Chemisry, 1994, 122(1): 9-14.
[47] CHELLASAMY V, THANGADURAI P.Structural and electrochemical investigations of nanostructured NiTiO₃ in acidic environment[J]. Frontiers of Materials Science, 2017, 11(2): 162-170.
[48] ZHU J, CHEN X B, SHEN J C.Lanthanum distribution in SrBi₄-_xLa_xTi₄O₁₅[J]. Materials Letters, 2005, 59(12): 1581-1584.
[49] MAMAT M H, PARIMON N, ISMAIL A S, et al.Structural, optical, and electrical evolution of sol-gel-immersion grown nickel oxide nanosheet array films on aluminium doping[J]. Journal of Materials Science-Materials in Electronics, 2019, 30(10): 9916-9930.
[50] HE X M, WANG F, LIU H, et al.Fabrication of highly dispersed NiTiO₃@TiO₂ yellow pigments with enhanced NIR reflectance[J]. Materials Letters, 2017, 208(8): 82-85.
[51] ACHER L, JI H, GARINO N, et al.Thermochromic properties of pure NiTiO₃ and its Cu- or Co-doped derivatives[J]. Ceramics International, 2023, 49(8): 12267-12273.
[52] RAHIMI-NASRABADI M, AHMADI F, EGHBALI- ARANI M.Novel route to synthesize nanocrystalline nickel titanate in the presence of amino acids as a capping agent[J]. Journal of Materials Science-Materials in Electronics, 2016, 27(11): 11873-11878.
[53] TONG Y P, FU J, CHEN Z.Synthesis, characterization, and NIR reflectance of highly dispersed NiTiO₃ and NiTiO₃/TiO₂ composite pigments[J]. Journal of Nanomaterials, 2016, 2016: 5464978.
[54] WANG J, SUN J Y, HUANG J, et al.Synthesis and its characterization of silver sulfide/nickel titanate/chitosan nanocomposites for photocatalysis and water splitting under visible light, and antibacterial studies[J]. Materials Chemistry and Physics, 2021, 272: 124990.
[55] CRAWFORD S E, OHODNICKI P R, BALTRUS J P.Materials for the photoluminescent sensing of rare earth elements: challenges and opportunities[J]. Journal of Materials Chemistry C, 2020, 8(24): 7975-8006.
[56] DUNG N V, HAI N N, NGOC T V D, et al. Optical, ferroelectric, and magnetic properties of NiTiO₃-CoFe₂O₄ composites prepared by one-step sol-gel method[J]. Journal of Materials Science-Materials in Electronics, 2022, 33(23): 18910-18921.
[57] FENNIE C J.Ferroelectrically induced weak ferromagnetism by design[J]. Physical Review Letters, 2008, 100(16): 167203.
[58] UEHARA M, AMANO Y, MIZUNO T, et al.Lattice distortion and piezoelectricity enhancement in GaN by alloying with group III and rare-earth elements: a comparative experimental study[J]. Physica Status Solidi- Rapid Research Letters, 2023: 2300087.