贵金属Pd-X(X=Ag, Ni, Sn)体系的相图热力学研究

doi:10.19976/j.cnki.43-1448/TF.2022003

Abstract
Figure/Table
References
Related Citation (2)

Download: PDF (591 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract Based on the critical re-assessment on the phase diagram and thermodynamic data available in literature of the Pd-X(X=Ag, Ni, Sn) systems, Gibbs energies of the liquid and FCC_A1 phases in three binary systems were described by the substitutional solution model. Three phase, PdSn₂, PdSn₃ and PdSn₄,were described by the sublattice model of (Pd,Sn)₁Sn₂, (Pd)_0.25(Pd,Sn)_0.75, and (Pd)_0.2(Pd,Sn)_0.8, respectively. Thermodynamic parameters for the Pd-X(X=Ag, Ni, Sn) systems were then obtained by the CALPHAD (calculation of phase diagram) approach. The presently obtained thermodynamic parameters can describe the measured phase diagram and thermodynamic properties more reasonably comparing with the previous reports, especially in the phase diagram of Pd-Ag system and enthalpies of mixing of FCC_A1 in both Pd-Ag and Pd-Ni systems, as well as the Sn-rich side of the phase diagram of the Pd-Sn system. Comprehensive comparisons between the calculated results and experimental data indicated the accuracy of the presently obtained thermodynamic parameters.

Key words： Pd-X (X=Ag,Ni,Sn) CALPHAD phase diagrams thermodynamic property

Received: 11 January 2022 Published: 19 July 2022

ZTFLH:

TG113.12

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LIAO Lin
	LIU Shuhong
	DU Yong

Cite this article:

LIAO Lin,LIU Shuhong,DU Yong. Thermodynamic investigation on the Pd-X(X=Ag, Ni, Sn) systems of the precious metals[J]. Materials Science and Engineering of Powder Metallurgy, 2022, 27(3): 246-256.

URL:

http://pmbjb.csu.edu.cn/EN/10.19976/j.cnki.43-1448/TF.2022003 OR http://pmbjb.csu.edu.cn/EN/Y2022/V27/I3/246

[1] LI J F, AGYAKWA P A, JOHNSON C M.Kinetics of Ag₃Sn growth in Ag-Sn-Ag system during transient liquid phase soldering process[J]. Acta Materialia, 2010, 58(9): 3429-3443.
[2] 余强, 刘文胜, 马运柱, 等. 等温时效对Cu/Sn-3.5Ag/ Ni(P)UBM互连焊接件界面微观组织及剪切性能的影响[J]. 粉末冶金材料科学与工程, 2017, 22(3): 390-398.
YU Qiang, LIU Wensheng, MA Yunzhu, et al.Effects of isothermal aging on interface microstructure and shear properties of Cu/Sn-3.5Ag/Ni(P) UBM interconnection solder joints[J]. Materials Science and Engineering of Powder Metallurgy, 2017, 22(3): 390-398.
[3] HE H, HUANG S, YE Y, et al.Microstructure and mechanical properties of Cu joints soldered with a Sn-based composite solder, reinforced by metal foam[J]. Journal of Alloys and Compounds, 2020, 845(2): 156240.
[4] 刘文胜, 汤娅, 马运柱, 等. 回流次数对Au80Sn20/Cu焊点显微组织及剪切性能的影响[J]. 粉末冶金材料科学与工程, 2016, 21(2): 303-310.
LIU Wensheng, TANG Ya, MA Yunzhu, et al.Effects of multiple reflows on microstructure and shear properties of Au80Sn20/Cu joint[J]. Materials Science and Engineering of Powder Metallurgy, 2016, 21(2): 303-310.
[5] GHOSH G.Interfacial microstructure and the kinetics of interfacial reaction in diffusion couples between Sn-Pb solder and Cu/Ni/Pd metallization[J]. Acta Materialia, 2000, 48(14): 3719-3738.
[6] ZHAO P, PECHT M G, KANG S, et al.Assessment of Ni/Pd/Au-Pd and Ni/Pd/Au-Ag preplated leadframe packages subject to electrochemical migration and mixed flowing gas tests[J]. IEEE Transactions on Components and Packaging Technologies, 2006, 29(4): 818-826.
[7] DU Y, LIU S H, ZHANG L J, et al.An overview on phase equilibria and thermodynamic modeling in multicomponent Al alloys: focusing on the Al-Cu-Fe-Mg-Mn-Ni-Si-Zn system[J]. Calphad, 2011, 35(3): 427-445.
[8] 刘树红, 金波, 傅太白, 等. 相图热力学数据库及其计算软件: 过去、现在和将来[J]. 中国科学: 化学, 2019, 49(7): 966-977.
LIU Shuhong, JIN Bo, FU Taibai, et al.Thermodynamic databases and software: past, present and future[J]. Science in China Chemistry: Chemistry, 2019, 49(7): 966-977.
[9] GHOSH G, KANTNER C, OLSON G B.Thermodynamic modeling of the Pd-X (X= Ag, Co, Fe, Ni) systems[J]. Journal of Phase Equilibria, 1999, 20(3): 295-308.
[10] LUEF C, PAUL A, FLANDORFER H, et al.Enthalpies of mixing of metallic systems relevant for lead-free soldering: Ag-Pd and Ag-Pd-Sn[J]. Journal of Alloys and Compounds, 2005, 391(1): 67-76.
[11] CHUDNENKO K V.Thermodynamic properties of components in the Ag-Au-Pd system[J]. Russian Journal of Inorganic Chemistry, 2020, 65(1): 94-99.
[12] FENG D, TASKINEN P.Thermodynamic properties of silver- palladium alloys determined by a solid state electrochemical method[J]. Journal of Materials Science, 2014, 49(16): 5790-5798.
[13] RUER R.Über die legierungen des palladiums mit silber[J]. Zeitschriftfur Anorganische Chemie, 1906, 51(1): 315-319.
[14] SAVITSKIJ E M, PRAVOVEROVN L.Kurnakov phases in the palladium-silver system[J]. Russian Journal of Inorganic Chemistry, 1961, 6(3): 253-254.
[15] SOPOUŠEK J, ZEMANOVÁ A, VŘEŠŤÁL J, et al. Experimental determination of phase equilibria and reassessment of Ag-Pd system[J]. Journal of Alloys and Compounds, 2010, 504(2): 431-434.
[16] BIDWELL L R, SPEISER R.The relative thermodynamic properties of solid nickel-palladium alloys[J]. Acta Metallurgica, 1965, 13(2): 61-70.
[17] CUI S, WANG J, YOU Z, et al.Critical evaluation and thermodynamic modeling of the Pd-Sn system[J]. Intermetallics, 2020, 126(4): 106945.
[18] NYLÉN J, GARCIA F J G, MOSEL B D, et al. Structural relationships, phase stability and bonding of compounds PdSn_n (n= 2, 3, 4)[J]. Solid State Science, 2004, 6(1): 147-155.
[19] JANDL I, RICHTER K W.The Sn-rich corner of the system Ni-Pd-Sn: a phase diagram study[J]. Journal of Alloys and Compounds, 2017, 697(1): 310-317.
[20] VATOLIN N A, TIMOFEEV A I, DUBININ E L.Vapour pressure of liquid palladium alloys[J]. Russian Journal of Inorganic Chemistry, 1971, 45(8): 1149-1150.
[21] LAURIE G H, PRATT J N.Electronic constitution and partial thermodynamic properties of liquid tin+palladium+silver alloys[J]. Transactions of the Faraday Society, 1964, 60(2): 1391-1401.
[22] RAYCHAUDHURI, KUMAR P.Mass Spectrometric and Galvanic Cell Studies of the Thermodynamic Properties of Solid Silver-palladium Alloys[M]. Evanston, USA: Pro Quest, 1971: 111-185.
[23] HEINRICH F.Metallographische mitteilungen aus dem institut für physikalische chemie der universität göttingen. LXXXVI. Über die legierungen des palladiums mit nickel[J]. Zeitschrift fur Anorganische Chemie, 1913, 83(1): 322-327.
[24] FRAENKEL W, STERN A.Über gold-palladium- nickellegierungen[J]. Zeitschrift fur Anorganische Chemie, 1927, 166(1): 164-165.
[25] BIDWELL L R, SPEISER R.Unit-cell dimensions of Ni-Pd alloys at 25 ℃ and 900 ℃[J]. Acta Crystallographica, 1964, 17(11): 1473-1474.
[26] HULTGREN R, ZAPFFE C A.An X-ray study of the iron-palladium and nickel-palladium systems[J]. Transactions of the American Institute of Mining and Metallurgical Engineers, 1939, 133(2): 58-68.
[27] VATOLIN N A, KOZLOV Y S, PASTUKHOV E A.Structure and physicochemical properties of palladium-nickel and palladium-silicon melts[J]. Russian Metallurgy, 1977, (5): 226-227.
[28] OISHI T, NISHI S, ONO K.Thermodynamic studies of the liquid Ni-Pd alloys by mass spectrometric and solid state EMF measurements[J]. Transactions of the Japan Institute of Metals, 1986, 27(4): 288-292.
[29] KNIGHT J R, RHYS D W.The systems palladium-indium and palladium-tin[J]. Journal of the Less Common Metals, 1959, 1(4): 292-303.
[30] SCHUBERT K, LUKAS H, MEIßNER H, et al. Zum aufbau der systeme kobalt-gallium, palladium-gallium, palladium-zinn und verwandter legierungen[J]. International Journal of Materials Research, 1959, 50(9): 534-540.
[31] ELLNER M.Zusammenhang zwischen strukturellen und thermo-dynamischen eigenschaftenbei phase nderkupfer-familie in T₁₀-B₄-systemen[J]. Journal of the Less Common Metals, 1981, 78(2): 21-32.
[32] SARAH N, ALASAFI K, SCHUBERT K.Kristallstruktur von Pd₂₀Sn₁₃, Pd₆AgPb₄ und Ni₁₃ZnGe₈[J]. International Journal of Materials Research, 1981, 72(7): 517-520.
[33] ROMAKA V V, TKACHUK A, ROMAKA V A.Pd₅Sn₇—a novel binary stannide in Pd-Sn system[J]. Journal of Alloys and Compounds, 2010, 496(1/2): L7-L9.
[34] SCHALLER H J, BRODOWSKY H.Thermodynamic properties of Pd-Sn alloys[J]. Zeitschrift fur Metallkunde, 1978, 69(2): 87-93.
[35] GUADAGNO J R, POOL M J.Liquid palladium-tin alloys[J]. The Journal of Physical Chemistry, 1968, 72(7): 2535-2538.
[36] BRYANT A W, BUGDEN W G, PRATT J N.Calorimetric and galvanic cell studies of the thermodynamic properties of palladium-tin alloys[J]. Acta Metallurgica, 1970, 18(1): 101-107.
[37] CHROMIK R R, COTTS E J.A Study of the kinetics and energetics of solid state reactions in Pd/Sn diffusion couples[J]. MRS Online Proceedings Library Archive, 1995, 398(2): 233-239.
[38] CICCIOLI A, BALDUCCI G, GIGLI G, et al.Vaporization behaviour and some thermodynamic properties of the Pd-In, Pd-Pb, Pd-Sn systems[J]. Intermetallics, 2000, 8(3): 195-201.
[39] AMORE S, DELSANTE S, PARODI N, et al.Thermochemistry of Pd-In, Pd-Sn and Pd-Zn alloy systems[J]. Thermochimica Acta, 2009, 481(1/2): 1-6.
[40] DINSDALE A T.SGTE data for pure elements[J]. Calphad, 1991, 15(4): 317-425.
[41] ANDERSSON J O, HELANDER T, HÖGLUND L, et al. Thermo-Calc & DICTRA, computational tools for materials science[J]. Calphad, 2002, 26(2): 273-312.