稀土离子掺杂调控MIL-101的电子结构促进电催化氮还原反应

doi:10.19976/j.cnki.43-1448/TF.2024033

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Abstract Electrocatalytic nitrogen reduction reaction (eNRR) is considered as an effective strategy for producing $NH_{3}/NH_{4}^{+}$ with low concentrations under environmental conditions, and designing appropriate catalysts is the key to efficiently driving eNRR. This study used a hydrothermal method to prepare MIL-101 catalyst and investigated the effects of hydrothermal temperature and Gd element doping on the eNRR performance of MIL-101 catalyst. The results show that 150-M-101 has the highest crystallinity and eNRR performance (NH₃ yield of 11.5 μg/(h·mg), Faraday efficiency of 30.5%). The surface of MIL-101-0.5Gd is concave, exposing the internal rough pore structure, improving the apparent activity of the catalyst. At the same time, the increase of oxygen vacancy concentration optimizes the characteristic activity of the catalyst, the NH₃ yield and Faraday efficiency at 0.1 mol/L LiClO₄ electrolyte and -1.3 V potential are 16.7 μg/(h·mg) and 37.6%, respectively, which are better than undoped 150-MIL-101. The catalyst also has good long-term stability.

Key words： rare earth ion defective engineering electrocatalytic nitrogen reduction morphological control electronic transfer promotion

Received: 10 April 2024 Published: 12 August 2024

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	Articles by authors
	YANG Tonghui
	YUE Song
	GONG Weiwei
	WANG Renqing
	HU Weida
	LIU Xiaopan
	GAO Pengzhao
	QIN Hang
	GUO Wenming
	XIAO Hanning

Cite this article:

YANG Tonghui,YUE Song,GONG Weiwei, et al. Rare earth ion doping regulates the electronic structure of MIL-101 to promote electrocatalytic nitrogen reduction reaction[J]. Materials Science and Engineering of Powder Metallurgy, 2024, 29(3): 231-245.

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http://pmbjb.csu.edu.cn/EN/10.19976/j.cnki.43-1448/TF.2024033 OR http://pmbjb.csu.edu.cn/EN/Y2024/V29/I3/231

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