统一外推模型与传统外推模型在Ag-Bi-Cu、In-Li-Sn和Al-Sn-Zn三元合金系混合焓计算中的性能对比

doi:10.19976/j.cnki.43-1448/TF.2024120

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Abstract The thermodynamic properties of alloy solutions are crucial for evaluating phase stability and calculating phase diagrams. Accurate prediction of these data is of great significance for the development of new alloy materials, optimization of metallurgical processes, improvement of product quality, and reduction of production costs. In this study, the unified extrapolation model (UEM) was employed to calculate the enthalpy of mixing of the Ag-Bi-Cu, In-Li-Sn, and Al-Sn-Zn ternary alloy systems at various compositions. The results were compared with those obtained from several commonly used extrapolation models, including the Kohler, Muggianu, Toop, and general solution models, as well as experimental data reported in the literatures. The findings indicate that UEM provides overall superior predictions compared to other models, demonstrating higher accuracy and applicability in the prediction of thermodynamic properties.

Key words： multicomponent alloy solution thermodynamic model extrapolation model thermodynamic property enthalpy of mixing

Received: 31 December 2024 Published: 28 July 2025

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	LÜ Yang
	LÜ Qiwen
	LIAO Linghui
	LIU Dongyun
	JU Tianhua

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LÜ Yang,LÜ Qiwen,LIAO Linghui, et al. Performance comparison of unified and traditional extrapolation models in calculating enthalpy of mixing of Ag-Bi-Cu, In-Li-Sn, and Al-Sn-Zn ternary alloy systems[J]. Materials Science and Engineering of Powder Metallurgy, 2025, 30(3): 193-203.

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http://pmbjb.csu.edu.cn/EN/10.19976/j.cnki.43-1448/TF.2024120 OR http://pmbjb.csu.edu.cn/EN/Y2025/V30/I3/193

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