Sm3+/Ce3+共掺杂B2O3-Al2O3-SiO2玻璃的结构和激光吸收性能

doi:10.19976/j.cnki.43-1448/TF.2023012

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Abstract B₂O₃-Al₂O₃-SiO₂-Sm₂O₃-xCeO₂ (x is 0-6%, molar fraction) glasses were prepared by solid-phase melting method with Sm³⁺/Ce³⁺ co-doping in boron-aluminosilicate glasses (composition 43B₂O₃-25Al₂O₃-32SiO₂) with the help of X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), UV-Vis-NIR spectrophotometer (UV-VIS-NIR) and other characterization methods to study the structure and laser absorption properties of the glasses. The results show that all samples are glassy with uniform distribution of Sm³⁺ and Ce³⁺. The percentage of bridging oxygen in the glasses increases from 60.12% to 63.82% with the CeO₂ molar fraction increasing from 0 to 2%, and decreases to 59.41% when the CeO₂ molar fraction increases to 6%. The laser absorption performance of the glasses is best at 2%CeO₂ molar fraction, with the diffuse absorption peak at 1 076 nm and the diffuse reflectance of 48.10%. The Sm³⁺/Ce³⁺ co-doped boron-aluminosilicate glass is a promising material for laser absorption at 1.06 μm wavelength.

Key words： Sm³⁺/Ce³⁺ co-doping B₂O₃-Al₂O₃-SiO₂ glass materials 1.06 μm laser laser absorption property

Received: 03 March 2023 Published: 04 May 2023

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	LÜ Xuejuan
	SU Yuchang
	WANG Lirong
	LU Qingye

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LÜ Xuejuan,SU Yuchang,WANG Lirong, et al. Structure and laser absorption property of Sm³⁺/Ce³⁺ co-doped B₂O₃-Al₂O₃-SiO₂ glasses[J]. Materials Science and Engineering of Powder Metallurgy, 2023, 28(2): 151-159.

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http://pmbjb.csu.edu.cn/EN/10.19976/j.cnki.43-1448/TF.2023012 OR http://pmbjb.csu.edu.cn/EN/Y2023/V28/I2/151

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