磁响应光子晶体四氧化三铁的制备及磁致变色

doi:10.19976/j.cnki.43-1448/TF.2023001

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Abstract Magnetically responsive ferroferric oxide (Fe₃O₄) nanoparticles were prepared by solvothermal method using ferric trichoride (FeCl₃) as the iron source and poly (styrene sulfonic acid-co-maleic acid) (PSSMA) sodium salt with two different chemical structures as surfactants. The effects of PSSMA surfactants with different structures and reaction conditions on the morphology, particle size, and photonic properties of Fe₃O₄nanoparticles were investigated. The results show that the Fe₃O₄particles are nearly spherical and surface is rough when using PSSMA with n(SS)∶n(MA)=1∶1 as surfactant in strong alkali environment, and particle size increases with increasing water content. Using PSSMA with n(SS)∶n(MA)=3∶1 as surfactant in weak alkali environment, the particles are regular spherical and surface is smooth, and the size increases with increasing Fe³⁺ content. It is more suitable for the generation of superparamagnetic Fe₃O₄ nanoparticles with uniform particle size and good monodispersity in weak alkaline environment due to the more abundant sulfonic acid group on the surface. This Fe₃O₄ nanoparticle dispersion system can rapidly form ordered photonic crystal nanoparticles under the action of external magnetic field, and obtain excellent tunable structure color.

Key words： magnetically responsive photonic crystals ferroferric oxide PSSMA particle size magnetic discoloration

Received: 01 January 2023 Published: 04 May 2023

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	TIAN Zhaoxia
	WU Zhisheng
	XIAO Wei
	XU Gaojie
	LIU Fenghua

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TIAN Zhaoxia,WU Zhisheng,XIAO Wei, et al. Preparation and magnetochromic discoloration of ferroferric oxide magnetically responsive photonic crystals[J]. Materials Science and Engineering of Powder Metallurgy, 2023, 28(2): 129-140.

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http://pmbjb.csu.edu.cn/EN/10.19976/j.cnki.43-1448/TF.2023001 OR http://pmbjb.csu.edu.cn/EN/Y2023/V28/I2/129

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