Structure and laser absorption property of Sm3+/Ce3+ co-doped B2O3-Al2O3-SiO2 glasses

L&#x000dc; Xuejuan; SU Yuchang; WANG Lirong; LU Qingye

doi:10.19976/j.cnki.43-1448/TF.2023012

Materials Science and Engineering of Powder Metallurgy >

2023 , Vol. 28 >Issue 2: 151 - 159

DOI: https://doi.org/10.19976/j.cnki.43-1448/TF.2023012

Engineering and Technology

Structure and laser absorption property of Sm³⁺/Ce³⁺ co-doped B₂O₃-Al₂O₃-SiO₂ glasses

LÜ Xuejuan ,
SU Yuchang ,
WANG Lirong ,
LU Qingye

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School of Materials Science and Engineering, Central South University, Changsha 410083, China

Received date: 2023-03-03

Revised date: 2023-03-28

Online published: 2023-05-04

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Abstract

B₂O₃-Al₂O₃-SiO₂-Sm₂O₃-xCeO₂ (x is 0-6%, molar fraction) glasses were prepared by solid-phase melting method with Sm³⁺/Ce³⁺ co-doping in boron-aluminosilicate glasses (composition 43B₂O₃-25Al₂O₃-32SiO₂) with the help of X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), UV-Vis-NIR spectrophotometer (UV-VIS-NIR) and other characterization methods to study the structure and laser absorption properties of the glasses. The results show that all samples are glassy with uniform distribution of Sm³⁺ and Ce³⁺. The percentage of bridging oxygen in the glasses increases from 60.12% to 63.82% with the CeO₂ molar fraction increasing from 0 to 2%, and decreases to 59.41% when the CeO₂ molar fraction increases to 6%. The laser absorption performance of the glasses is best at 2%CeO₂ molar fraction, with the diffuse absorption peak at 1 076 nm and the diffuse reflectance of 48.10%. The Sm³⁺/Ce³⁺ co-doped boron-aluminosilicate glass is a promising material for laser absorption at 1.06 μm wavelength.

Key words： Sm³⁺/Ce³⁺ co-doping; B₂O₃-Al₂O₃-SiO₂; glass materials; 1.06 μm laser; laser absorption property

Cite this article

LÜ Xuejuan , SU Yuchang , WANG Lirong , LU Qingye . Structure and laser absorption property of Sm³⁺/Ce³⁺ co-doped B₂O₃-Al₂O₃-SiO₂ glasses[J]. Materials Science and Engineering of Powder Metallurgy, 2023 , 28(2) : 151 -159 . DOI: 10.19976/j.cnki.43-1448/TF.2023012

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